<div class="csl-bib-body">
<div class="csl-entry">Peresypkina, E., Stöger, B., Dinauer, S. B., & Virovets, A. V. (2022). Try Another Crystal: Crystal-Dependent Disorder of Pentaphosphaferrocene within the Same Crystallization. <i>Crystal Growth and Design</i>, <i>22</i>(6), 3870–3874. https://doi.org/10.1021/acs.cgd.2c00252</div>
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dc.identifier.issn
1528-7483
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/136868
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dc.description.abstract
The degree of disorder of [Cp″Fe(η⁵-P₅)] [Cp″ = η⁵-1,3-(tBu)₂C₅H₃] molecules with respect to their mirrored positions in the orthorhombic Pca21 space group varies from ∼1 to 24% depending on the single crystal chosen from the same sample for the X-ray structural determination. This unusual behavior is caused by stacking faults in adjacent layers parallel to the (001) direction giving rise to two polytypes. A comprehensive search in the Cambridge Structural Database revealed only a few similar examples of the crystal-dependent disorder caused by stacking faults. Moreover, crystals of [Cp″Fe(η⁵-P₅)] possessing a low amount of stacking faults demonstrate slight temperature-induced superstructural ordering (modulation) between 20 and 80 K, accompanied by a doubling of the b parameter (b′ -> 2 × b).
en
dc.language.iso
en
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dc.publisher
AMER CHEMICAL SOC
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dc.relation.ispartof
Crystal Growth and Design
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dc.subject
Condensed Matter Physics
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dc.subject
General Materials Science
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dc.subject
layers
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dc.subject
General Chemistry
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dc.subject
crystal structure
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dc.subject
crystals
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dc.subject
defects in solids
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dc.subject
disorder
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dc.title
Try Another Crystal: Crystal-Dependent Disorder of Pentaphosphaferrocene within the Same Crystallization
