<div class="csl-bib-body">
<div class="csl-entry">Kawamura, Y., Deminami, S., Takeda, K., Kuzuya, T., Salamakha, L., Michor, H., Bauer, E., Gouchi, J., Uwatoko, Y., Kawae, T., & Sekine, C. (2021). Crystallographic and superconducting properties of filled skutterudite SrOs₄P₁₂. <i>Physical Review B</i>, <i>103</i>(085139). https://doi.org/10.1103/PhysRevB.103.085139</div>
</div>
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dc.identifier.issn
2469-9950
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/137368
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dc.description.abstract
The crystallographic and physical properties of the recently discovered filled skutterudite superconductor SrOs4P12, synthesized by a high-pressure and -temperature technique, are studied by measuring electrical resistivity, specific heat, and magnetization, and by performing electronic band calculations. X-ray powder diffraction with Rietveld refinement indicates that the lattice parameter of SrOs4P12 is 8.093(2) Å and that fractional coordinates of the P site are [0, 0.3607(9), 0.1450(9)], which is also confirmed by calculations based on density functional theory. The electrical resistivity indicates a metallic nature of SrOs4P12, which is consistent with the density of states at Fermi energy with 7.5 (states/eV)/f.u. deduced from the electronic band calculations. The Sommerfeld coefficient γ and Einstein temperature ΘE of SrOs4P12 are deduced as γ∼26mJ/molK2 and ΘE∼150 K, respectively. A larger isotropic atomic displacement parameter Ueq of Sr compared to other atomic species as obtained from a Rietveld analysis and a specific heat anomaly around 30 K refers to anharmonic lattice vibrations of Sr in SrOs4P12. SrOs4P12 exhibits two superconducting transitions at Tc1=1.6 K and Tc2=1.0 K. Specific-heat data indicate that the observed superconductivity is of bulk nature with approximate volume fractions of 27% and 38% for superconductivity at Tc1 and Tc2, respectively. The electrical resistivity under field and pressure as well as the specific heat under field indicate that Tc1 is sensitive to the magnetic field and Tc2 is sensitive to pressure. The results show that Tc2 is an s-wave weakly coupled superconductor with an electron-phonon mass enhancement λep∼0.47.
en
dc.language.iso
en
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dc.publisher
AMER PHYSICAL SOC
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dc.relation.ispartof
Physical Review B
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dc.subject
alkaline earth metals
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dc.subject
superconductivity
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dc.title
Crystallographic and superconducting properties of filled skutterudite SrOs₄P₁₂
en
dc.type
Artikel
de
dc.type
Article
en
dc.contributor.affiliation
Muroran Institute of Technology, Japan
-
dc.contributor.affiliation
Muroran Institute of Technology, Japan
-
dc.contributor.affiliation
Muroran Institute of Technology, Japan
-
dc.contributor.affiliation
Muroran Institute of Technology, Japan
-
dc.contributor.affiliation
The University of Tokyo, Japan
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dc.contributor.affiliation
The University of Tokyo, Japan
-
dc.contributor.affiliation
Kyushu University, Japan
-
dc.contributor.affiliation
Muroran Institute of Technology, Japan
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dc.type.category
Original Research Article
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tuw.container.volume
103
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tuw.container.issue
085139
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tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
-
wb.publication.intCoWork
International Co-publication
-
tuw.researchTopic.id
M3
-
tuw.researchTopic.name
Metallic Materials
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tuw.researchTopic.value
100
-
dcterms.isPartOf.title
Physical Review B
-
tuw.publication.orgunit
E138-03 - Forschungsbereich Functional and Magnetic Materials
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tuw.publisher.doi
10.1103/PhysRevB.103.085139
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dc.identifier.eissn
2469-9969
-
dc.description.numberOfPages
9
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tuw.author.orcid
0000-0002-5581-0858
-
tuw.author.orcid
0000-0003-1642-5946
-
tuw.author.orcid
0000-0003-1301-4690
-
wb.sci
true
-
wb.sciencebranch
Physik, Astronomie
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wb.sciencebranch.oefos
1030
-
wb.facultyfocus
Physik der Materie
de
wb.facultyfocus
Physics of Matter
en
wb.facultyfocus.faculty
E130
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item.languageiso639-1
en
-
item.openairecristype
http://purl.org/coar/resource_type/c_2df8fbb1
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item.fulltext
no Fulltext
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item.openairetype
research article
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item.grantfulltext
none
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item.cerifentitytype
Publications
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crisitem.author.dept
Muroran Institute of Technology
-
crisitem.author.dept
Muroran Institute of Technology
-
crisitem.author.dept
Muroran Institute of Technology
-
crisitem.author.dept
Muroran Institute of Technology
-
crisitem.author.dept
E138-03 - Forschungsbereich Functional and Magnetic Materials
-
crisitem.author.dept
E138-03 - Forschungsbereich Functional and Magnetic Materials
-
crisitem.author.dept
E138-03 - Forschungsbereich Functional and Magnetic Materials