<div class="csl-bib-body">
<div class="csl-entry">Pálvölgyi, Á. M., Ehrschwendtner, F., Schnürch, M., & Bica-Schröder, K. (2022). Photocatalyst-free hydroacylations of electron-poor alkenes and enones under visible-light irradiation. <i>Organic and Biomolecular Chemistry</i>, <i>20</i>(36), 7245–7249. https://doi.org/10.1039/d2ob01364a</div>
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dc.identifier.issn
1477-0520
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/139180
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dc.description.abstract
Herein we present a photocatalyst- and additive-free radical hydroacylation of electron-poor double bonds under mild reaction conditions. Using 4-acyl-Hantzsch ester radical reservoirs, various Michael acceptors, enones and para-quinone methide substrates could be used. The protocol enabled further derivatizations and it could also be extended to a few unactivated alkenes. Moreover, the nature of the radical process was also investigated.
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dc.language.iso
en
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dc.publisher
ROYAL SOC CHEMISTRY
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dc.relation.ispartof
Organic and Biomolecular Chemistry
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dc.subject
Catalysis
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dc.subject
Electrons
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dc.subject
Esters
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dc.subject
Free Radicals
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dc.subject
Alkenes
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dc.subject
Photochemical Processes
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dc.title
Photocatalyst-free hydroacylations of electron-poor alkenes and enones under visible-light irradiation