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<div class="csl-entry">Sombut, P., Puntscher, L., Atzmueller, M., Jakub, Z., Reticcioli, M., Meier, M., Parkinson, G. S., & Franchini, C. (2022). Role of Polarons in Single-Atom Catalysts: Case Study of Me₁ [Au₁, Pt₁, and Rh₁] on TiO₂(110). <i>Topics in Catalysis</i>, <i>65</i>(17–18), 1620–1630. https://doi.org/10.1007/s11244-022-01651-0</div>
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dc.identifier.issn
1022-5528
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/139669
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dc.description.abstract
The local environment of metal-oxide supported single-atom catalysts plays a decisive role in the surface reactivity and related catalytic properties. The study of such systems is complicated by the presence of point defects on the surface, which are often associated with the localization of excess charge in the form of polarons. This can affect the stability, the electronic configuration, and the local geometry of the adsorbed adatoms. In this work, through the use of density functional theory and surface-sensitive experiments, we study the adsorption of Rh₁, Pt₁, and Au₁ metals on the reduced TiO₂(110) surface, a prototypical polaronic material. A systematic analysis of the adsorption configurations and oxidation states of the adsorbed metals reveals different types of couplings between adsorbates and polarons. As confirmed by scanning tunneling microscopy measurements, the favored Pt₁ and Au₁ adsorption at oxygen vacancy sites is associated with a strong electronic charge transfer from polaronic states to adatom orbitals, which results in a reduction of the adsorbed metal. In contrast, the Rh₁ adatoms interact weakly with the excess charge, which leaves the polarons largely unaffected. Our results show that an accurate understanding of the properties of single-atom catalysts on oxide surfaces requires a careful account of the interplay between adatoms, vacancy sites, and polarons.
en
dc.language.iso
en
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dc.publisher
SPRINGER/PLENUM PUBLISHERS
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dc.relation.ispartof
Topics in Catalysis
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dc.subject
Density functional theory
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dc.subject
Polarons
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dc.subject
Scanning probe microscope
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dc.subject
Single-atom catalysis
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dc.subject
TiO₂(110) surface
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dc.title
Role of Polarons in Single-Atom Catalysts: Case Study of Me₁ [Au₁, Pt₁, and Rh₁] on TiO₂(110)