<div class="csl-bib-body">
<div class="csl-entry">Weinberger, P., Giester, G., & Steinhauser, G. (2020). Controlling Complexation Behavior of Early Lanthanides via the Subtle Interplay of their Lewis Acidity with the Chemical Stability of 5,5’-(Azobis)tetrazolide. <i>Journal of Inorganic and General Chemistry</i>, <i>646</i>(23–24), 1882–1885. https://doi.org/10.1002/zaac.202000384</div>
</div>
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dc.identifier.issn
0044-2313
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/141272
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dc.description.abstract
Two novel nitrogen‐rich lanthanide compounds of 5,5'‐(azobis)tetrazolide (ZT) were synthesized and structurally characterized. The dinuclear, isostructural compounds [Ce₂(ZT)₂CO₃(H₂O)₁₂] · 4 H₂O (1) and [Pr₂(ZT)₂CO₃(H₂O)₁₂]·4 H₂O (2) were synthesized via two independent routes. Compound 1 was obtained after partial Lewis acidic decomposition of ZT by Ceᴵⱽ in aqueous solution of (NH₄)₂Ce(NO₃)₆ and Na₂ZT. Compound 2 was obtained by crystallization from aqueous solutions of Pr(NO₃)₃, Na₂ZT, and Na₂CO₃. By X‐ray diffraction analysis at 200 K, it was found that the trivalent lanthanide cations are bridged by a bidentate carbonato ligand and each cation is further coordinated by six H₂O ligands and one ZT ligand thus being ninefold coordinated.
en
dc.publisher
WILEY-V C H VERLAG GMBH
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dc.relation.ispartof
Journal of Inorganic and General Chemistry
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dc.subject
Inorganic Chemistry
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dc.subject
X-ray diffraction
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dc.subject
Lanthanides
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dc.subject
Lewis acidity
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dc.subject
Dinuclear complex
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dc.subject
5
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dc.subject
5´-Azobis[tetrazolide]
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dc.title
Controlling Complexation Behavior of Early Lanthanides via the Subtle Interplay of their Lewis Acidity with the Chemical Stability of 5,5'-(Azobis)tetrazolide
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dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
1882
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dc.description.endpage
1885
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dc.type.category
Original Research Article
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tuw.container.volume
646
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tuw.container.issue
23-24
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tuw.journal.peerreviewed
true
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tuw.peerreviewed
true
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tuw.researchTopic.id
M8
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tuw.researchTopic.name
Structure-Property Relationship
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tuw.researchTopic.value
100
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dcterms.isPartOf.title
Journal of Inorganic and General Chemistry
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tuw.publication.orgunit
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie
