<div class="csl-bib-body">
<div class="csl-entry">Steinacher, M., Svatunek, D., Weil, M., Mohammadi, B., & Gärtner, P. (2022). Synthesis and conformational analysis of a potentially super-armed glucuronidation donor. <i>Monatshefte Für Chemie - Chemical Monthly</i>. https://doi.org/10.1007/s00706-022-03009-4</div>
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dc.identifier.issn
0026-9247
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/142148
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dc.description.abstract
The concise synthesis of a potentially “super-armed” glucuronidation donor is reported. The α-anomer was crystallized and analyzed by single crystal X-ray diffraction. The pyranose ring was found to be in a twist-boat conformation in the solid state. To confirm the relevance of this finding for the solution state, and explain the failure of analysis by NMR, DFT calculations were performed. They revealed the twist-boat to be the dominant among a group of several possible conformers at ambient temperature.
en
dc.language.iso
en
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dc.publisher
SPRINGER WIEN
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dc.relation.ispartof
Monatshefte für Chemie - Chemical Monthly
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dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
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dc.subject
Carbohydrates
en
dc.subject
Conformation
en
dc.subject
Crystal structure
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dc.subject
Protecting groups
en
dc.title
Synthesis and conformational analysis of a potentially super-armed glucuronidation donor
