<div class="csl-bib-body">
<div class="csl-entry">Cognigni, A., Palvögyi, Á. M., Schröder, C., Peterlik, H., Müllner, A. R. M., Zirbs, R., Weil, M., & Bica, K. (2019). Surface-Active Ionic Liquids in Catalytic Water Splitting. <i>Australian Journal of Chemistry</i>, <i>72</i>(2), 34–41. https://doi.org/10.1071/ch18104</div>
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dc.identifier.issn
0004-9425
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/142435
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dc.description.abstract
We report the application of surface-active ionic liquids as ligands and optional reaction media in iridium-catalyzed water
oxidations. Three novel catalysts with N,N-dialkylimidazolidin-2-ylidene ligands based on amphiphilic imidazolium ionic
liquids were synthesized and characterized. Excellent turn-over frequencies of up to 0.92 s^-^1 were obtained in catalytic
water splitting, and activity was maintained for five consecutive catalytic cycles, with an overall turn-over number of 8967.
The addition of external surface-active ionic liquid showed unexpected behaviour, because strongly enhanced initial
reaction rates were observed
en
dc.language.iso
en
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dc.publisher
CSIRO PUBLISHING
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dc.relation.ispartof
Australian Journal of Chemistry
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dc.subject
General Chemistry
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dc.title
Surface-Active Ionic Liquids in Catalytic Water Splitting
