<div class="csl-bib-body">
<div class="csl-entry">Pecak, J., Käfer, M., Fleissner, S., Artner, W., & Kirchner, K. (2022). Synthesis and characterization of cobalt SCS pincer complexes. <i>Monatshefte Für Chemie - Chemical Monthly</i>, <i>153</i>(7–8), 545–549. https://doi.org/10.1007/s00706-022-02949-1</div>
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dc.identifier.issn
0026-9247
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/142507
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dc.description.abstract
The synthesis and characterization of two Co(II) complexes stabilized by a tridentate SCS pincer ligand are described. Paramagnetic [Co(κ3-SCSCH2-Et)2] and [Co(κ3-SCSCH2-tBu)(κ2-SCSCH2-tBu)] were obtained via transmetalation protocol from CoBr2 and S(C-Br)SCH2-R (R = Et, tBu). Oxidation of the latter with [Cp2Fe]PF6 affords the diamagnetic 18 VE complex [Co(κ3-SCSCH2-tBu)2]PF6. X-ray structures and DFT calculations are presented.
en
dc.language.iso
en
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dc.publisher
SPRINGER WIEN
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dc.relation.ispartof
Monatshefte für Chemie - Chemical Monthly
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dc.subject
Cobalt
en
dc.subject
DFT
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dc.subject
Pincer complex
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dc.subject
Transmetalation
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dc.title
Synthesis and characterization of cobalt SCS pincer complexes
