<div class="csl-bib-body">
<div class="csl-entry">Gusev, A. N., Shul´Gin, V. F., Braga, E. V., Nemec, I., Minaev, B. F., Baryshnikov, G. V., Trávníček, Z., Agren, H., Eremenko, I. L., Lyssenko, K. A., & Linert, W. (2018). Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence. <i>Polyhedron</i>, <i>155</i>, 202–208. https://doi.org/10.1016/j.poly.2018.08.019</div>
</div>
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dc.identifier.issn
0277-5387
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/144467
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dc.description.abstract
The present article reports on the syntheses, crystal structures and luminescence properties of three solvate forms of a zinc(II) complex containing 4-{(E)-[(2-fluorophenyl)imino]methyl}-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one (HL). The reaction of zinc(II) acetate with the HL ligand in ethanol and acetonitrile led to the formation of two solvate analogues [Zn(L)2]·Solv (Solv - ethanol (1) and acetonitrile (2)). The properties of the [Zn(L)2]·Solv complexes were investigated by UV-Vis absorption and fluorescence emission spectroscopy, and density functional theory calculations. Bader's topological analysis was performed to investigate the electronic peculiarities of Zn(II) polyhedra and non-covalent interactions within crystal packing of studied solvates.
en
dc.language.iso
en
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dc.relation.ispartof
Polyhedron
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dc.subject
Inorganic Chemistry
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dc.subject
Physical and Theoretical Chemistry
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dc.subject
Materials Chemistry
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dc.subject
Schiff base
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dc.subject
Zinc(II) complex
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dc.subject
Photophysical properties
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dc.subject
Density functional theory
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dc.subject
Crystal structures.
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dc.title
Synthesis and photophysical properties of Zn(II) Schiff base complexes possessing strong solvent-dependent solid-state fluorescence
en
dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
202
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dc.description.endpage
208
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dc.type.category
Original Research Article
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tuw.container.volume
155
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tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
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wb.publication.intCoWork
International Co-publication
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tuw.researchTopic.id
M2
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tuw.researchTopic.name
Materials Characterization
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tuw.researchTopic.value
100
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dcterms.isPartOf.title
Polyhedron
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tuw.publication.orgunit
E163-01-2 - Forschungsgruppe Koordinationschemie und bio-anorganische Chemie
