<div class="csl-bib-body">
<div class="csl-entry">Müller, D., Knoll, C., Seifried, M., Welch, J. M., Giester, G., Reissner, M., & Weinberger, P. (2018). Halogenated Alkyltetrazoles for the Rational Design of Fell Spin-Crossover Materials: Fine-Tuning of the Ligand Size. <i>Chemistry – A European Journal</i>, <i>24</i>(20), 5271–5280. https://doi.org/10.1002/chem.201704656</div>
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dc.identifier.issn
0947-6539
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/144826
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dc.description.abstract
1-(3-Halopropyl)-1H-tetrazoles and their corresponding FeII spin-crossover complexes have been investigated in a combined experimental and theoretical study. Halogen substitution was found to positively influence the spin transition, shifting the transition temperature about 70 K towards room temperature. Halogens located at the ω position were found to be too far away from the coordinating tetrazole moiety to have an electronic impact on the spin transition. The subtle variation of the steric demand of the ligand in a highly comparable series was found to have a comparatively large impact on the spin-transition behavior, which highlights the sensitivity of the effect to subtle structural changes.
en
dc.language.iso
en
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dc.publisher
Wiley
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dc.relation.ispartof
Chemistry – A European Journal
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dc.subject
General Chemistry
en
dc.subject
Catalysis
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dc.subject
Organic Chemistry
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dc.title
Halogenated Alkyltetrazoles for the Rational Design of Fell Spin-Crossover Materials: Fine-Tuning of the Ligand Size