<div class="csl-bib-body">
<div class="csl-entry">Corva, M., Ferrari, A., Rinaldi, M., Feng, Z., Roiaz, M., Rameshan, C., Rupprechter, G., Constantini, R., Dell´Angela, M., Pastore, G., Comelli, G., Seriani, N., & Vesselli, E. (2018). Vibrational fingerprint of localized excitons in a two-dimensional metal-organic crystal. <i>Nature Communications</i>, <i>9</i>(4703). https://doi.org/10.1038/s41467-018-07190-1</div>
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dc.identifier.issn
2041-1723
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/145327
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dc.description.abstract
macrocycles, each hosting a single FeN₄ center, where a single carbon monoxide molecule can adsorb. In this heme-like biomimetic model system, excitons are generated by visible laser light upon a spin transition associated with the layer 2D crystallinity, and are simultaneously detected via the carbon monoxide ligand stretching mode at room temperature and near-ambient pressure. The proposed mechanism is supported by the results of infrared and time-resolved pump-probe spectroscopies, and by ab initio theoretical methods, opening a path towards the handling of exciton dynamics on 2D biomimetic crystals.
en
dc.language.iso
en
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dc.relation.ispartof
Nature Communications
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dc.subject
General Physics and Astronomy
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dc.subject
General Chemistry
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dc.subject
Multidisciplinary
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dc.subject
General Biochemistry, Genetics and Molecular Biology
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dc.title
Vibrational fingerprint of localized excitons in a two-dimensional metal-organic crystal
