<div class="csl-bib-body">
<div class="csl-entry">Taublaender, M. J., Glöcklhofer, F., Marchetti-Deschmann, M., & Unterlass, M. M. (2018). Green and Rapid Hydrothermal Crystallization and Synthesis of Fully Conjugated Aromatic Compounds. <i>Angewandte Chemie International Edition</i>, <i>57</i>(38), 12270–12274. https://doi.org/10.1002/anie.201801277</div>
</div>
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dc.identifier.issn
1433-7851
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/145679
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dc.description.abstract
Highly fused, fully conjugated aromatic compounds are interesting candidates for organic electronics. With higher crystallinity their electronic properties improve. It is shown here that the crystallization of three archetypes of such molecules-pentacenetetrone, indigo, and perinone-can be achieved hydrothermally. Given their molecular structure, this is a truly startling finding. In addition, it is demonstrated that perinone can also be synthesized in solely high‐temperature water from the starting compounds naphthalene bisanhydride and o‐phenylene diamine without the need for co‐solvents or catalysts. The transformation can be drastically accelerated by the application of microwave irradiation. This is the first report on the hydrothermal generation of two fused heterocycles.
en
dc.language.iso
en
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dc.relation.ispartof
Angewandte Chemie International Edition
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dc.subject
General Chemistry
en
dc.subject
Catalysis
en
dc.title
Green and Rapid Hydrothermal Crystallization and Synthesis of Fully Conjugated Aromatic Compounds
en
dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
12270
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dc.description.endpage
12274
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dc.type.category
Original Research Article
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tuw.container.volume
57
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tuw.container.issue
38
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tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
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tuw.researchTopic.id
M7
-
tuw.researchTopic.id
M2
-
tuw.researchTopic.id
M1
-
tuw.researchTopic.name
Special and Engineering Materials
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tuw.researchTopic.name
Materials Characterization
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tuw.researchTopic.name
Surfaces and Interfaces
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tuw.researchTopic.value
25
-
tuw.researchTopic.value
25
-
tuw.researchTopic.value
50
-
dcterms.isPartOf.title
Angewandte Chemie International Edition
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tuw.publication.orgunit
E163-03-2 - Forschungsgruppe Molekulare Chemie und Chemische Biologie
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tuw.publication.orgunit
E164-01-1 - Forschungsgruppe Massenspektrometrische Bio- und Polymeranalytik