<div class="csl-bib-body">
<div class="csl-entry">Gusev, A. N., Shulgin, V. F., Riush, I. O., Lyssenko, K. A., Eremenko, I. L., & Linert, W. (2017). A new family of Co(II), Ni(II), Fe(II) triple helicate systems on 5,5′-di(pyridin-2-yl)-3,3′-bi(1,2,4-triazole) basis: Synthesis, structure and magnetic studies. <i>Inorganica Chimica Acta</i>, <i>456</i>, 136–141. https://doi.org/10.1016/j.ica.2016.10.040</div>
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dc.identifier.issn
0020-1693
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/146207
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dc.description.abstract
Reaction of 5,5′-bi(pyridin-2-yl)-3,3′-bi(1,2,4-triazole) (H2L) with Ni(II), Co(II) and Fe(II) nitrates generates three novel dinuclear triple helicate complexes. Obtained compounds fully characterized by elemental analysis, UV-Vis and IR-spectroscopy. Moreover, the triple-helical structure of was con-firmed by X-ray in solid state and by ESMS-studies in solution. Complexation behavior was studied by UV-Vis spectrophotometric titration experiments that revealed the formation of species with 2:3 metal - ligand molar ratio. The magnetic properties of the Ni(II), Co(II) and Fe(II) are dominated by weak antiferromagnetic interactions (altogether with spin-orbital coupling in the Co(II) case). The magnetic studies of air and vacuum dried Iron complex samples indicate that lattice water molecules directly affect the magnetic behavior of these complexes.
en
dc.language.iso
en
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dc.publisher
ELSEVIER SCIENCE SA
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dc.relation.ispartof
Inorganica Chimica Acta
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dc.subject
Inorganic Chemistry
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dc.subject
Physical and Theoretical Chemistry
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dc.subject
Materials Chemistry
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dc.subject
Dinuclear triple helicate
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dc.subject
Triazole
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dc.subject
Magnetic studies
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dc.title
A new family of Co(II), Ni(II), Fe(II) triple helicate systems on 5,5′-di(pyridin-2-yl)-3,3′-bi(1,2,4-triazole) basis: Synthesis, structure and magnetic studies
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dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
136
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dc.description.endpage
141
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dc.type.category
Original Research Article
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tuw.container.volume
456
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tuw.journal.peerreviewed
true
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tuw.peerreviewed
true
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wb.publication.intCoWork
International Co-publication
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tuw.researchTopic.id
M2
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tuw.researchTopic.name
Materials Characterization
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tuw.researchTopic.value
100
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dcterms.isPartOf.title
Inorganica Chimica Acta
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tuw.publication.orgunit
E163-01-2 - Forschungsgruppe Koordinationschemie und bio-anorganische Chemie