DC Element
Wert
Sprache
dc.contributor.author
Glatz, Matthias
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dc.contributor.author
Schröder-Holzhacker, Christian
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dc.contributor.author
Bichler, Bernhard
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dc.contributor.author
Stöger, Berthold
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dc.contributor.author
Mereiter, Kurt
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dc.contributor.author
Veiros, Luis F.
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dc.contributor.author
Kirchner, Karl
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dc.date.accessioned
2020-06-27T15:26:06Z
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dc.date.issued
2016-10
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dc.identifier.citation
<div class="csl-bib-body"> <div class="csl-entry">Glatz, M., Schröder-Holzhacker, C., Bichler, B., Stöger, B., Mereiter, K., Veiros, L. F., &#38; Kirchner, K. (2016). Synthesis and characterization of cationic dicarbonyl Fe(II) PNP pincer complexes. <i>Monatshefte Für Chemie - Chemical Monthly</i>. https://doi.org/10.1007/s00706-016-1811-x</div> </div>
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dc.identifier.issn
0026-9247
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dc.identifier.uri
https://resolver.obvsg.at/urn:nbn:at:at-ubtuw:3-1980
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/146
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dc.description
The final publication is available at Springer via <a href="https://doi.org/10.1007/s00706-016-1811-x" target="_blank">https://doi.org/10.1007/s00706-016-1811-x</a>.
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dc.description.abstract
In the present work, we have prepared a series of octahedral Fe(II) complexes of the type trans-[Fe(PNP)(CO)2Cl]+—PNP are tridentate pincer-type ligands based on 2,6-diaminopyridine. These complexes are formed irrespective of the size of the substituents at the phosphorus sites and whether cis-[Fe(PNP)(Cl2)(CO)] or trans-[Fe(PNP)(Cl2)(CO)] are reacted with CO in the presence of 1 equiv of silver salts. X-ray structures of representative complexes are presented. Based on simple bonding considerations the selective formation of trans-dicarbonyl Fe(II) complexes is unexpected. In fact, DFT calculations confirm that trans-dicarbonyl complexes are indeed thermodynamically disfavored over the respective cis-dicarbonyl compounds, but are favored for kinetic reasons.
en
dc.description.sponsorship
Austrian Science Fund (FWF)
-
dc.description.sponsorship
Fundação para a Ciência e a Tecnologia (FCT)
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dc.language
English
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dc.language.iso
en
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dc.publisher
Springer
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dc.relation.ispartof
Monatshefte für Chemie - Chemical Monthly
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dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
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dc.subject
Iron complexes
en
dc.subject
PNP pincer ligands
en
dc.subject
Carbon monoxide
en
dc.subject
DFT calculations
en
dc.title
Synthesis and characterization of cationic dicarbonyl Fe(II) PNP pincer complexes
en
dc.type
Article
en
dc.type
Artikel
de
dc.rights.license
Creative Commons Namensnennung 4.0 International
de
dc.rights.license
Creative Commons Attribution 4.0 International
en
dc.contributor.affiliation
TU Wien, Österreich
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dc.contributor.affiliation
Centro Cardiovascular da Universidade de Lisboa, Portugal
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dc.relation.grantno
P28866-N34
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dc.relation.grantno
UID/QUI/00100/2013.
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dcterms.dateSubmitted
2016-05-16
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dc.rights.holder
The Author(s) 2016.
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dc.type.category
Original Research Article
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tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
-
tuw.version
vor
-
wb.publication.intCoWork
International Co-publication
-
dcterms.isPartOf.title
Monatshefte für Chemie - Chemical Monthly
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tuw.publication.orgunit
E163 - Institut für Angewandte Synthesechemie
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tuw.publisher.doi
10.1007/s00706-016-1811-x
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dc.date.onlinefirst
2016-08-06
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dc.identifier.eissn
1434-4475
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dc.identifier.libraryid
AC11360172
-
dc.identifier.urn
urn:nbn:at:at-ubtuw:3-1980
-
tuw.author.orcid
0000-0002-0087-474X
-
tuw.author.orcid
0000-0003-0419-1222
-
tuw.author.orcid
0000-0001-5841-3519
-
tuw.author.orcid
0000-0003-0872-6159
-
dc.rights.identifier
CC BY 4.0
de
dc.rights.identifier
CC BY 4.0
en
wb.sci
true
-
item.languageiso639-1
en
-
item.grantfulltext
open
-
item.cerifentitytype
Publications
-
item.openairetype
research article
-
item.openairecristype
http://purl.org/coar/resource_type/c_2df8fbb1
-
item.fulltext
with Fulltext
-
item.openaccessfulltext
Open Access
-
crisitem.author.dept
E163-01-1 - Forschungsgruppe Organometallische Chemie und Katalyse
-
crisitem.author.dept
E163 - Institut für Angewandte Synthesechemie
-
crisitem.author.dept
E163 - Institut für Angewandte Synthesechemie
-
crisitem.author.dept
E057-04 - Fachbereich Röntgenzentrum
-
crisitem.author.dept
E164 - Institut für Chemische Technologien und Analytik
-
crisitem.author.dept
University of Lisbon
-
crisitem.author.dept
E163-01-1 - Forschungsgruppe Organometallische Chemie und Katalyse
-
crisitem.author.orcid
0000-0002-0087-474X
-
crisitem.author.orcid
0000-0001-5841-3519
-
crisitem.author.orcid
0000-0003-0872-6159
-
crisitem.author.parentorg
E163-01 - Forschungsbereich Anorganische Chemie
-
crisitem.author.parentorg
E150 - Fakultät für Technische Chemie
-
crisitem.author.parentorg
E150 - Fakultät für Technische Chemie
-
crisitem.author.parentorg
E057 - Facilities und Zentren
-
crisitem.author.parentorg
E150 - Fakultät für Technische Chemie
-
crisitem.author.parentorg
E163-01 - Forschungsbereich Anorganische Chemie
-
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