<div class="csl-bib-body">
<div class="csl-entry">Mautner, A., Steinbauer, B., Russmüller, G., Lieber, R., Koch, T., Stampfl, J., & Liska, R. (2016). Vinyl carbonate photopolymers with improved mechanical properties for biomedical applications. <i>DESIGNED MONOMERS AND POLYMERS</i>, <i>19</i>(5), 437–444. https://doi.org/10.1080/15685551.2016.1169378</div>
</div>
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dc.identifier.issn
1385-772X
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/148683
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dc.description.abstract
Abstract
Recently, vinyl carbonates have been demonstrated to be a versatile alternative to acrylates and methacrylates in biomedical applications as they exhibit photoreactivity and mechanical properties on a level or even above (meth)acrylates. Furthermore, much lower cytotoxicity as well as degradation via a surface erosion mechanism qualify them for medical use. However, it is highly desirable to improve the mechanical properties of vinyl carbonates to reach the performance of PLA. Thus, the main focus of this study lies on designing vinyl carbonates with suitable functional groups that are capable of augmenting mechanical properties of vinyl carbonates, e.g. cyclic structures or urethane groups, and implementing them into the vinyl carbonate structures. Resulting monomers were tested regarding their photoreactivity and cytotoxicity. Furthermore, cured specimens were investigated concerning their mechanical properties. In addition, the thiol-ene reaction was utilized to further improve photoreactivity. The new vinyl carbonates exhibit excellent biocompatibility and photoreactivity that can be significantly enhanced through the addition of thiols onto the level of highly photoreactive acrylates. Most importantly, results showed that the mechanical properties could be improved onto the level of PLA and above.
en
dc.language.iso
en
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dc.publisher
TAYLOR & FRANCIS LTD
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dc.relation.ispartof
DESIGNED MONOMERS AND POLYMERS
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dc.subject
General Chemistry
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dc.subject
mechanical properties
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dc.subject
biocompatibility
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dc.subject
photopolymerization
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dc.subject
Materials Chemistry
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dc.subject
General Chemical Engineering
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dc.subject
Polymers and Plastics
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dc.subject
Vinyl carbonate
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dc.subject
thiol-ene reaction
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dc.title
Vinyl carbonate photopolymers with improved mechanical properties for biomedical applications
en
dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
437
-
dc.description.endpage
444
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dc.type.category
Original Research Article
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tuw.container.volume
19
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tuw.container.issue
5
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tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
-
tuw.researchTopic.id
M6
-
tuw.researchTopic.id
M7
-
tuw.researchTopic.name
Biological and Bioactive Materials
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tuw.researchTopic.name
Special and Engineering Materials
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tuw.researchTopic.value
50
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tuw.researchTopic.value
50
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dcterms.isPartOf.title
DESIGNED MONOMERS AND POLYMERS
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tuw.publication.orgunit
E163-02-1 - Forschungsgruppe Polymerchemie und Technologie
-
tuw.publication.orgunit
E308-02 - Forschungsbereich Polymer- und Verbundwerkstoffe
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tuw.publisher.doi
10.1080/15685551.2016.1169378
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dc.identifier.eissn
1568-5551
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dc.description.numberOfPages
8
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wb.sci
true
-
wb.sciencebranch
Chemie
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wb.sciencebranch
Chemische Verfahrenstechnik
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wb.sciencebranch.oefos
1040
-
wb.sciencebranch.oefos
2040
-
wb.facultyfocus
Chemistry and Technology of Materials
de
wb.facultyfocus
Chemistry and Technology of Materials
en
wb.facultyfocus.faculty
E150
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item.fulltext
no Fulltext
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item.cerifentitytype
Publications
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item.openairecristype
http://purl.org/coar/resource_type/c_2df8fbb1
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item.languageiso639-1
en
-
item.openairetype
research article
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item.grantfulltext
none
-
crisitem.author.dept
E163 - Institut für Angewandte Synthesechemie
-
crisitem.author.dept
E308-02-1 - Forschungsgruppe Strukturpolymere
-
crisitem.author.dept
E308-02 - Forschungsbereich Polymer- und Verbundwerkstoffe