<div class="csl-bib-body">
<div class="csl-entry">Gusev, A. N., Shulgin, V. F., Beyjyyev, E., Alexandrov, G. G., Eremenko, I. L., & Linert, W. (2015). Anion-triggered coordination mode of the new chelating ligand 1,3-bis[5-(2-pyrimidinyl)-1,2,4-triazol-3-yl]propane. <i>Polyhedron</i>, <i>85</i>, 525–529. https://doi.org/10.1016/j.poly.2014.09.020</div>
</div>
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dc.identifier.issn
0277-5387
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/150393
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dc.description.abstract
The flexible ditopic ligand 1,3-bis[5-(2-pyrimidinyl)-1,2,4-triazol-3-yl]propane H2L displays remarka-ble versatility in the coordination mode depending on the counter anion. With copper(II) nitrate H2L acts as a tetradentate chelate forming a mononuclear complex. The reaction with copper(II) perchlorate gives a centrosymmetric dinuclear complex coordinating the deprotonated form of the ligand. Reaction with copper(II) chloride leads to a pentanuclear complex in which binuclear species are bridged by a CuCl2 fragment. All complexes were crystallographically characterized. Additionally, magnetic prop-erties of bi- and pentanuclear complexes were studied.
en
dc.language.iso
en
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dc.publisher
Elsevier
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dc.relation.ispartof
Polyhedron
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dc.subject
Inorganic Chemistry
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dc.subject
X-ray diffraction
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dc.subject
Physical and Theoretical Chemistry
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dc.subject
Materials Chemistry
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dc.subject
2
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dc.subject
magnetic properties
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dc.subject
1
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dc.subject
4-triazole
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dc.subject
Cu(II) complex
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dc.title
Anion-triggered coordination mode of the new chelating ligand 1,3-bis[5-(2-pyrimidinyl)-1,2,4-triazol-3-yl]propane
en
dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
525
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dc.description.endpage
529
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dc.type.category
Original Research Article
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tuw.container.volume
85
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tuw.journal.peerreviewed
true
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tuw.peerreviewed
true
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tuw.researchTopic.id
M2
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tuw.researchTopic.name
Materials Characterization
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tuw.researchTopic.value
100
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dcterms.isPartOf.title
Polyhedron
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tuw.publication.orgunit
E163-01-2 - Forschungsgruppe Koordinationschemie und bio-anorganische Chemie