<div class="csl-bib-body">
<div class="csl-entry">Gusev, A. N., Shulgin, V. F., Zamnius, E. A., Ricci, M., Minin, V. V., Aleksandrov, G. G., Eremenko, I. L., & Linert, W. (2015). Copper(II) complexes with flexible polydentate bispycolylamidrazone ligands: synthesis, structure and magnetic studies. <i>Inorganica Chimica Acta</i>, <i>430</i>, 120–124. https://doi.org/10.1016/j.ica.2015.03.005</div>
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dc.identifier.issn
0020-1693
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/150592
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dc.description.abstract
Three novel dinuclear copper(II) complex with spacer-armed bispicolylamidrazone ligands were synthesized and characterized by elemental analysis, UV-VIS and IR-spectroscopy and X-ray crystal analysis. Structural analysis demonstrated quite long distances (6-8 Å) between copper(II) ions. Despite these long distances, antiferromagnetic interaction between paramagnetic centers was found. Temperature dependences of magnetic susceptibility and EPR studies are in agreement with an antiferromagnetic dinuclear behavior in solid state yielding exchange parameters of -2J of 1.47 to 5.9 cm-1.
en
dc.publisher
Elsevier
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dc.relation.ispartof
Inorganica Chimica Acta
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dc.subject
Inorganic Chemistry
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dc.subject
X-ray diffraction
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dc.subject
Physical and Theoretical Chemistry
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dc.subject
EPR
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dc.subject
Materials Chemistry
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dc.subject
Copper(II) complexes
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dc.subject
amidrazone
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dc.subject
magnetochemistry
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dc.subject
antiferromagnetism
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dc.title
Copper(II) complexes with flexible polydentate bispycolylamidrazone ligands: synthesis, structure and magnetic studies
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dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
120
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dc.description.endpage
124
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dc.type.category
Original Research Article
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tuw.container.volume
430
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tuw.journal.peerreviewed
true
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tuw.peerreviewed
true
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tuw.researchTopic.id
M2
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tuw.researchTopic.name
Materials Characterization
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tuw.researchTopic.value
100
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dcterms.isPartOf.title
Inorganica Chimica Acta
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tuw.publication.orgunit
E163-01-2 - Forschungsgruppe Koordinationschemie und bio-anorganische Chemie