<div class="csl-bib-body">
<div class="csl-entry">Kalogiouri, N., Manousi, N., FERRACANE, A., ZACHARIADIS, G., Koundouras, S., SAMANIDOU, V. F., Tranchida, P., Mondello, L., & Rosenberg, E. E. (2022, September 7). <i>A volatile fingerprinting strategy for wine aging authentication using SPME-Arrow coupled to comprehensive GCxGC-MS combined with advanced chemometrics</i> [Poster Presentation]. RAFA 2022 - 33rd International Symposium on Recent Advances in Food Analysis, Prag, Czechia. http://hdl.handle.net/20.500.12708/153252</div>
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/153252
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dc.description.abstract
In a global food market, Protected Designation of Origin (PDO) wines are highly appreciated for the period of aging that allows the evolution of unique organoleptic properties, and thus, the guarantee of the vintage age is a critical authenticity issue [1]. The coupling of SPME-Arrow to GCxGC/MS analysis in combination with chemometric techniques could revolutionize the field of wine authenticity with the establishment of characteristic volatile markers according to the vintage age. In this work, an SPME-Arrow-GCxGC/MS method was optimized and used for the determination of volatile markers in 24 monovarietal red wine samples belonging to the PDO Xinomavro Naoussa, produced during 4 different years (1998, 2005, 2008 and 2015), in Northern Greece. Overall, 258 volatile compounds were tentatively identified. The data matrix was further processed with multivariate techniques to establish mathematical models and reveal volatile markers for each vintage age. A partial least square – discriminant analysis (PLS-DA) model was developed and successfully classified all the samples to the proper class according to the vintage age with an explained total variance of 95.7%. Variant Importance in Projection (VIP) algorithm was used to calculate the VIP scores of the determined volatiles and distinguish the most important features that affect the discrimination, revealing markers [2]. The developed prediction model was validated and the analyzed samples were classified with 100% accuracy according to the vintage age, on the basis of their volatile fingerprint.
en
dc.language.iso
en
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dc.subject
wine authenticity
en
dc.subject
2D-GC
en
dc.subject
SPME arrow
en
dc.subject
chemometrics
en
dc.subject
volatile fingerprint
en
dc.title
A volatile fingerprinting strategy for wine aging authentication using SPME-Arrow coupled to comprehensive GCxGC-MS combined with advanced chemometrics
en
dc.type
Presentation
en
dc.type
Vortrag
de
dc.contributor.affiliation
Aristotle University of Thessaloniki, Greece
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dc.contributor.affiliation
Aristotle University of Thessaloniki, Greece
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dc.contributor.affiliation
University of Messina, Italy
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dc.contributor.affiliation
Aristotle University of Thessaloniki, Greece
-
dc.contributor.affiliation
Aristotle University of Thessaloniki, Greece
-
dc.contributor.affiliation
Aristotle University of Thessaloniki, Greece
-
dc.contributor.affiliation
University of Messina, Italy
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dc.contributor.affiliation
University of Messina, Italy
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dc.type.category
Poster Presentation
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tuw.researchTopic.id
X1
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tuw.researchTopic.name
Beyond TUW-research foci
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tuw.researchTopic.value
100
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tuw.publication.orgunit
E164-01-2 - Forschungsgruppe Oberflächen-, Spurenanalytik und Chemometrie
-
tuw.author.orcid
0000-0001-6183-7857
-
tuw.author.orcid
0000-0002-1516-8012
-
tuw.author.orcid
0000-0003-1372-3040
-
tuw.author.orcid
0000-0001-6191-6301
-
tuw.author.orcid
0000-0003-1868-2081
-
tuw.author.orcid
0000-0002-8493-1106
-
tuw.author.orcid
0000-0002-6357-0815
-
tuw.author.orcid
0000-0002-8890-675X
-
tuw.event.name
RAFA 2022 - 33rd International Symposium on Recent Advances in Food Analysis
en
tuw.event.startdate
06-09-2022
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tuw.event.enddate
09-09-2022
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tuw.event.online
On Site
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tuw.event.type
Event for scientific audience
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tuw.event.place
Prag
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tuw.event.country
CZ
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tuw.event.institution
University of Chemistry and Technology Prague & Wageningen University
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tuw.event.presenter
Kalogiouri, Natasa
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tuw.event.track
Multi Track
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wb.sciencebranch
Chemie
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wb.sciencebranch.oefos
1040
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wb.sciencebranch.value
100
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item.openairecristype
http://purl.org/coar/resource_type/c_18co
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item.openairetype
conference poster not in proceedings
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item.fulltext
no Fulltext
-
item.languageiso639-1
en
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item.grantfulltext
none
-
item.cerifentitytype
Publications
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crisitem.author.dept
Aristotle University of Thessaloniki
-
crisitem.author.dept
Aristotle University of Thessaloniki
-
crisitem.author.dept
TU Wien
-
crisitem.author.dept
Aristotle University of Thessaloniki
-
crisitem.author.dept
Aristotle University of Thessaloniki
-
crisitem.author.dept
Aristotle University of Thessaloniki
-
crisitem.author.dept
University of Messina
-
crisitem.author.dept
University of Messina
-
crisitem.author.dept
E164-01-2 - Forschungsgruppe Oberflächen-, Spurenanalytik und Chemometrie
-
crisitem.author.orcid
0000-0001-6183-7857
-
crisitem.author.orcid
0000-0003-1372-3040
-
crisitem.author.orcid
0000-0001-6191-6301
-
crisitem.author.orcid
0000-0002-8493-1106
-
crisitem.author.orcid
0000-0002-6357-0815
-
crisitem.author.orcid
0000-0002-8890-675X
-
crisitem.author.parentorg
E164-01 - Forschungsbereich Imaging und Instrumentelle Analytische Chemie