<div class="csl-bib-body">
<div class="csl-entry">Zeni, W., Müller, D., Knoll, C., Seifried, M., Giester, G., Reissner, M., & Weinberger, P. (2022, August 29). <i>Advanced Host-Guest Chemistry in Second Generation Spin-Switchable Hofmann Type Networks</i> [Poster Presentation]. 44th International Conference on Coordination Chemistry (ICCC 2022), Rimini, Italy. http://hdl.handle.net/20.500.12708/153254</div>
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/153254
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dc.description.abstract
A main goal of nowadays spin crossover (SCO) research is the development of materials suitable for technological applications. Multifunctional materials, combining the SCO effect with an additional property (e.g. luminescence, NLO, etc.) would notably broaden the scope of applicability. Currently, we focus on the development of spin-switchable metal organic frameworks with extended pore-size that could act as multifunctional materials by the mere incorporation of a functional guest. Starting from Hofmann-type networks - {Fe[Mᴵᴵ(CN)₄]∞} (M=Ni, Pd, Pt) layers stacked by symmetrical bifunctional N-ligands - an extension of the [Mᴵᴵ(CN)₄]²⁻ fragment was performed, by addition of an acetylene unit to the CN fragment (resulting in C≡C-C≡N fragment). This led to second generation Hofmann-type networks with hysteretic SCO behavior beyond room-temperature and extended pore size.
en
dc.description.sponsorship
Fonds zur Förderung der wissenschaftlichen Forschung (FWF)
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dc.language.iso
en
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dc.subject
Fe(II) spin crossover
en
dc.subject
Hofmann type network
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dc.subject
host-guest chemistry
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dc.title
Advanced Host-Guest Chemistry in Second Generation Spin-Switchable Hofmann Type Networks
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dc.type
Presentation
en
dc.type
Vortrag
de
dc.contributor.affiliation
University of Vienna, Austria
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dc.relation.grantno
P31076-N28
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dc.type.category
Poster Presentation
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tuw.project.title
Design von SCO-Liganden mit Azolen und Gruppe 14 Elementen
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tuw.researchinfrastructure
Röntgenzentrum
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tuw.researchTopic.id
M8
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tuw.researchTopic.name
Structure-Property Relationsship
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tuw.researchTopic.value
100
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tuw.publication.orgunit
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie
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tuw.author.orcid
0000-0002-3883-4188
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tuw.author.orcid
0000-0003-4172-6193
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tuw.event.name
44th International Conference on Coordination Chemistry (ICCC 2022)
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tuw.event.startdate
28-08-2022
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tuw.event.enddate
02-09-2022
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tuw.event.online
On Site
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tuw.event.type
Event for scientific audience
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tuw.event.place
Rimini
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tuw.event.country
IT
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tuw.event.institution
Societa Chimica Italiana
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tuw.event.presenter
Zeni, Willi
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wb.sciencebranch
Chemie
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wb.sciencebranch.oefos
1040
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wb.sciencebranch.value
100
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item.openairetype
conference poster not in proceedings
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item.languageiso639-1
en
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item.cerifentitytype
Publications
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item.fulltext
no Fulltext
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item.grantfulltext
none
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item.openairecristype
http://purl.org/coar/resource_type/c_18co
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crisitem.project.funder
FWF Fonds zur Förderung der wissenschaftlichen Forschung (FWF)
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crisitem.project.grantno
P31076-N28
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crisitem.author.dept
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie
-
crisitem.author.dept
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie
-
crisitem.author.dept
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie
-
crisitem.author.dept
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie