<div class="csl-bib-body">
<div class="csl-entry">FERRACANE, A., MANOUSI, N., Kalogiouri, N., Tranchida, P. Q., ZACHARIADIS, G., Mondello, L., & Rosenberg, E. E. (2022, September 7). <i>Elucidation of the volatile composition of honey samples by comprehensive two-dimensional gas chromatography – mass spectrometry combined with solid-phase microextraction Arrow</i> [Poster Presentation]. RAFA 2022 - 33rd International Symposium on Recent Advances in Separation Sciences, Prag, Czechia. http://hdl.handle.net/20.500.12708/153908</div>
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/153908
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dc.description.abstract
The elucidation of the volatile profile of honey samples is critical both for the evaluation of their quality and for their classification according to their botanical and geographical origin [1-2]. In this work, solid-phase microextraction Arrow (SPME Arrow) combined with comprehensive two- dimensional gas chromatography – mass spectrometry (GC×GC-MS) was used for the first time for the exploration of the volatile profile of honey samples. Due to the significantly higher sorption phase of SPME Arrow in comparison with conventional SPME fibers, the utilization of this technique results in enhanced sensitivity [3]. At the same time, GC×GC-MS serves as a powerful analytical tool for untargeted analysis due to its high sensitivity, selectivity, and peak capacity [4]. The main parameters that could potentially affect the extraction efficiency were optimized. Under optimum conditions, extraction was performed using divinylbenzene/polydimethylsiloxane (DVB/PDMS) SPME Arrow fibers and adsorption of the target analytes was carried out at 50 oC for 50 min under constant stirring. As a proof-of-concept, the proposed method was successfully employed for the analysis of multifloral and unifloral secretion and flower honey samples. The combination of GC×GC- MS and Arrow SPME enabled the determination of more than 200 compounds of different chemical classes including aldehydes, ketones, furanic compounds, and terpenes.
[1] L. Piasenzotto, L. Gracco, L. Conte, Solid phase microextraction (SPME) applied to honey quality control, J. Sci. Food Agric. 83 (2003) 1037–1044. [2] P.M. Da Silva, C. Gauche, L.V. Gonzaga, A.C.O. Costa, R. Fett, Honey: Chemical composition, stability and authenticity, Food Chem. 196 (2016) 309–323. [3] N. Manousi, E. Rosenberg, G.A. Zachariadis, Solid-phase microextraction arrow for the sampling of volatile organic compounds in milk samples, Separations. 7 (2020) 75. [4] G. Dugo, F.A. Franchina, M.R. Scandinaro, I. Bonaccorsi, N. Cicero, P.Q. Tranchida, L. Mondello, Elucidation of the volatile composition of marsala wines by using comprehensive two-dimensional gas chromatography, Food Chem. 142 (2014) 262–268.
en
dc.language.iso
en
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dc.subject
comprehensive two-dimensional gas chromatography
en
dc.subject
honey
en
dc.subject
volatile organic compounds
en
dc.subject
headspace solid phase microextraction
en
dc.title
Elucidation of the volatile composition of honey samples by comprehensive two-dimensional gas chromatography – mass spectrometry combined with solid-phase microextraction Arrow
en
dc.type
Presentation
en
dc.type
Vortrag
de
dc.contributor.affiliation
University of Messina, Italy
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dc.contributor.affiliation
Aristotle University of Thessaloniki, Greece
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dc.contributor.affiliation
University of Messina, Italy
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dc.contributor.affiliation
Aristotle University of Thessaloniki, Greece
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dc.contributor.affiliation
University of Messina, Italy
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dc.type.category
Poster Presentation
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tuw.researchTopic.id
X1
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tuw.researchTopic.name
Beyond TUW-research foci
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tuw.researchTopic.value
100
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tuw.publication.orgunit
E164-01-2 - Forschungsgruppe Oberflächen-, Spurenanalytik und Chemometrie
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tuw.author.orcid
0000-0003-1372-3040
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tuw.author.orcid
0000-0002-1516-8012
-
tuw.author.orcid
0000-0001-6183-7857
-
tuw.author.orcid
0000-0002-6357-0815
-
tuw.author.orcid
0000-0001-6191-6301
-
tuw.author.orcid
0000-0002-8890-675X
-
tuw.event.name
RAFA 2022 - 33rd International Symposium on Recent Advances in Separation Sciences
en
tuw.event.startdate
06-09-2022
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tuw.event.enddate
09-09-2022
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tuw.event.online
On Site
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tuw.event.type
Event for scientific audience
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tuw.event.place
Prag
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tuw.event.country
CZ
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tuw.event.institution
University of Chemistry and Technology Prague & Wageningen University
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tuw.event.presenter
FERRACANE, ANTONIO
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tuw.event.track
Multi Track
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wb.sciencebranch
Chemie
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wb.sciencebranch.oefos
1040
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wb.sciencebranch.value
100
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item.languageiso639-1
en
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item.grantfulltext
none
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item.cerifentitytype
Publications
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item.openairetype
conference poster not in proceedings
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item.openairecristype
http://purl.org/coar/resource_type/c_18co
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item.fulltext
no Fulltext
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crisitem.author.dept
TU Wien
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crisitem.author.dept
TU Wien
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crisitem.author.dept
Aristotle University of Thessaloniki
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crisitem.author.dept
University of Messina
-
crisitem.author.dept
Aristotle University of Thessaloniki
-
crisitem.author.dept
University of Messina
-
crisitem.author.dept
E164-01-2 - Forschungsgruppe Oberflächen-, Spurenanalytik und Chemometrie
-
crisitem.author.orcid
0000-0003-1372-3040
-
crisitem.author.orcid
0000-0002-1516-8012
-
crisitem.author.orcid
0000-0001-6183-7857
-
crisitem.author.orcid
0000-0001-6191-6301
-
crisitem.author.orcid
0000-0002-8890-675X
-
crisitem.author.parentorg
E164-01 - Forschungsbereich Imaging und Instrumentelle Analytische Chemie
