<div class="csl-bib-body">
<div class="csl-entry">Varain, L., Larisegger, S., Nelhiebel, M., & Fafilek, G. (2022, September 28). <i>Electrochemical Investigation and Modeling of Ion- and Water Transport Through Polymer Membranes</i> [Poster Presentation]. GDCH Electrochemistry 2022, Berlin, Germany.</div>
</div>
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/154393
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dc.description.abstract
The determination of diffusion coefficients in solid materials as a measure of particle mobility is of great scientific interest. This applies for intentional diffusion as for example in fuel cell- and dialysis membranes, as well as to unwanted diffusion in insulating materials. In any case, diffusion is a measure of performance.
Especially when considering solvated ion, the permeability of the solvent must also be taken into account.
This work presents a measurement method for the simultaneous determination of coupled ion diffusion and water permeability in polymer membranes. For this purpose, measurement methods for the determination of concentration-, volume- and membrane-potential changes are integrated into a miniaturized concentration cell.
For the general description of the coupled transport processes, a system of ordinary differential equations is developed.
Furthermore, a FEM model is developed in COMSOL Multiphysics®, which specifically simulates the ion distribution within the membrane and the resulting electrical fields.
A freestanding ion exchange membrane with largely known properties is then used to evaluate the new combined measurement setup.
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dc.description.sponsorship
Infineon Technologies Austria AG AFC1
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dc.language.iso
en
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dc.subject
ion diffusion, concentration cell, nafion, FEM simulation
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dc.title
Electrochemical Investigation and Modeling of Ion- and Water Transport Through Polymer Membranes
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dc.type
Presentation
en
dc.type
Vortrag
de
dc.relation.grantno
6000010583
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dc.type.category
Poster Presentation
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tuw.project.title
Multidisziplinäre Charakterisierung & Modellierung für innovative Prozess- & Produktin-tegration von Leistungshalbleitern
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tuw.researchTopic.id
M2
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tuw.researchTopic.name
Materials Characterization
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tuw.researchTopic.value
100
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tuw.publication.orgunit
E164-04-2 - Forschungsgruppe Elektrochemische Methoden und Korrosion
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tuw.event.name
GDCH Electrochemistry 2022
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tuw.event.startdate
27-09-2022
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tuw.event.enddate
30-09-2022
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tuw.event.online
On Site
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tuw.event.type
Event for scientific audience
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tuw.event.place
Berlin
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tuw.event.country
DE
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tuw.event.presenter
Varain, Lars
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wb.sciencebranch
Chemie
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wb.sciencebranch
Sonstige Technische Wissenschaften
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wb.sciencebranch.oefos
1040
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wb.sciencebranch.oefos
2119
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wb.sciencebranch.value
50
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wb.sciencebranch.value
50
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item.openairetype
Presentation
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item.openairetype
Vortrag
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item.grantfulltext
none
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item.cerifentitytype
Publications
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item.cerifentitytype
Publications
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item.languageiso639-1
en
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item.openairecristype
http://purl.org/coar/resource_type/c_18cf
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item.openairecristype
http://purl.org/coar/resource_type/c_18cf
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item.fulltext
no Fulltext
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crisitem.project.funder
Infineon Technologies Austria AG AFC1
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crisitem.project.grantno
4200237237
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crisitem.author.dept
E164-04-2 - Forschungsgruppe Elektrochemische Methoden und Korrosion
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crisitem.author.dept
E164 - Institut für Chemische Technologien und Analytik
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crisitem.author.dept
E164-04-2 - Forschungsgruppe Elektrochemische Methoden und Korrosion