<div class="csl-bib-body">
<div class="csl-entry">Vasiloiu, M., Rainer, D., Gärtner, P., Reichel, C., Schröder, C., & Bica, K. (2013). Basic chiral ionic liquids: A novel strategy for acid-free organocatalysis. <i>Catalysis Today</i>, <i>200</i>, 80–86. https://doi.org/10.1016/j.cattod.2012.07.002</div>
</div>
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dc.identifier.issn
0920-5861
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/154653
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dc.description.abstract
We present design, synthesis and application of basic chiral ionic liquids based on commercially available
(S)-proline. This new set of chiral ionic liquids was specifically designed to replace trifluoroacetic
acid in enamine-based organocatalysis for asymmetric C C bond formation. Based on their permanent
charge, these chiral ionic liquids could be applied as organocatalysts in asymmetric aldol reaction of 4-
nitrobenzaldehyde and acetone, and good yields and selectivities up to 80%ee could be obtained without
additional acid.
en
dc.language.iso
en
-
dc.publisher
ELSEVIER
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dc.relation.ispartof
Catalysis Today
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dc.subject
Chirality
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dc.subject
General Chemistry
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dc.subject
Ionic liquids
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dc.subject
Catalysis
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dc.subject
Organocatalysis
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dc.subject
Asymmetric synthesis
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dc.subject
Aldol reaction
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dc.title
Basic chiral ionic liquids: A novel strategy for acid-free organocatalysis
en
dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
80
-
dc.description.endpage
86
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dc.type.category
Original Research Article
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tuw.container.volume
200
-
tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
-
tuw.publication.invited
invited
-
tuw.researchTopic.id
X1
-
tuw.researchTopic.id
E6
-
tuw.researchTopic.name
außerhalb der gesamtuniversitären Forschungsschwerpunkte
-
tuw.researchTopic.name
Sustainable Production and Technologies
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tuw.researchTopic.value
50
-
tuw.researchTopic.value
50
-
dcterms.isPartOf.title
Catalysis Today
-
tuw.publication.orgunit
E163-03-3 - Forschungsgruppe Stereoselektive und nachhaltige Chemie
-
tuw.publication.orgunit
E163-03-5 - Forschungsgruppe Nachhaltige organische Synthese und Katalyse
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tuw.publisher.doi
10.1016/j.cattod.2012.07.002
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dc.identifier.eissn
1873-4308
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dc.description.numberOfPages
7
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tuw.author.orcid
0000-0002-2515-9873
-
wb.sci
true
-
wb.sciencebranch
Chemie
-
wb.sciencebranch
Technische Chemie, Brennstoff- und Mineralöltechnologie
-
wb.sciencebranch.oefos
13
-
wb.sciencebranch.oefos
26
-
wb.facultyfocus
Sustainability, Energy, Environment
de
wb.facultyfocus
Sustainability, Energy, Environment
en
wb.facultyfocus.faculty
E150
-
item.grantfulltext
none
-
item.openairetype
research article
-
item.openairecristype
http://purl.org/coar/resource_type/c_2df8fbb1
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item.cerifentitytype
Publications
-
item.languageiso639-1
en
-
item.fulltext
no Fulltext
-
crisitem.author.dept
E163 - Institut für Angewandte Synthesechemie
-
crisitem.author.dept
E163 - Institut für Angewandte Synthesechemie
-
crisitem.author.dept
E163-03-3 - Forschungsgruppe Stereoselektive und nachhaltige Chemie
-
crisitem.author.dept
Institute of Computational Biological Chemistry, University of Vienna, Austria
-
crisitem.author.dept
E163-03-5 - Forschungsgruppe Nachhaltige organische Synthese und Katalyse
-
crisitem.author.orcid
0000-0003-1569-5020
-
crisitem.author.orcid
0000-0002-2515-9873
-
crisitem.author.parentorg
E150 - Fakultät für Technische Chemie
-
crisitem.author.parentorg
E150 - Fakultät für Technische Chemie
-
crisitem.author.parentorg
E163-03 - Forschungsbereich Organische und Biologische Chemie
-
crisitem.author.parentorg
E163-03 - Forschungsbereich Organische und Biologische Chemie
