<div class="csl-bib-body">
<div class="csl-entry">Shul’gin, V. F., Konnik, O. V., Abkhairova, S. V., Gusev, A. N., Meshkova, S. B., Kiriyak, A. V., Rusanov, E. B., Hasegawa, M., & Linert, W. (2013). Anionic lanthanide complexes with 3-methyl-1-phenyl-4-formylpyrazole-5-one and hydroxonium as counter ion. <i>Inorganica Chimica Acta</i>, <i>402</i>, 33–38. https://doi.org/10.1016/j.ica.2013.03.044</div>
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dc.identifier.issn
0020-1693
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/154868
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dc.description.abstract
A series of [H3O]+[LnL4]-⋅nH2O complexes (n = 1-3, Ln = Nd, (1), Sm (2), Eu (3), Tb (4); HL = 3- methyl-1-phenyl-4-formylpyrazole-5-one) were synthesized and characterized. The structures of the SmIII and EuIII complexes were investigated by X-ray diffraction. The isostructutal crystalls 2 and 3 consist the tetrakis [LnL4]- anions which are linked by H-bonding with the hydroxonium counter- ion and water molecules. The lanthanide ion is situated in the center of distorted tetragonal antiprism formed by eight oxygen atoms of 4-formyl-5-hydroxypyrazolonate anions. The TbIII and SmIII complexes show strong luminescence in solid state, whereas the EuIII and NdIII complexes show low luminescence activity.
en
dc.language.iso
en
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dc.publisher
ELSEVIER SCIENCE SA
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dc.relation.ispartof
Inorganica Chimica Acta
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dc.subject
Luminescence
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dc.subject
Inorganic Chemistry
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dc.subject
Physical and Theoretical Chemistry
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dc.subject
Materials Chemistry
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dc.subject
Crystal structure
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dc.subject
4-Formyl-pyrazol-5-one
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dc.subject
Lanthanide complexes
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dc.title
Anionic lanthanide complexes with 3-methyl-1-phenyl-4-formylpyrazole-5-one and hydroxonium as counter ion
en
dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
33
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dc.description.endpage
38
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dc.type.category
Original Research Article
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tuw.container.volume
402
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tuw.journal.peerreviewed
true
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tuw.peerreviewed
true
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tuw.researchTopic.id
M2
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tuw.researchTopic.name
Materials Characterization
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tuw.researchTopic.value
100
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dcterms.isPartOf.title
Inorganica Chimica Acta
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tuw.publication.orgunit
E163-01-2 - Forschungsgruppe Koordinationschemie und bio-anorganische Chemie