<div class="csl-bib-body">
<div class="csl-entry">Gusev, A. N., Hasegawa, M., Shimizu, T., Fukawa, T., Sakurai, S., Nishchymenko, G. A., Shul’gin, V. F., Meshkova, S. B., & Linert, W. (2013). Synthesis, structure and luminescence studies of Eu(III), Tb(III), Sm(III), Dy(III) cationic complexes with acetylacetone and bis(5-(pyridine-2-yl)-1,2,4-triazol-3-yl)propane. <i>Inorganica Chimica Acta</i>, <i>406</i>, 279–284. https://doi.org/10.1016/j.ica.2013.04.006</div>
</div>
-
dc.identifier.issn
0020-1693
-
dc.identifier.uri
http://hdl.handle.net/20.500.12708/154907
-
dc.description.abstract
Synthesis, structure and luminescence studies of eight-coordinate Eu, Tb, Sm and Dy complexes of the type [Ln(acac)2(L)]Cl (Hacac = pentanedione-2,4 and L = bis(5-(pyridine-2-yl)-1,2,4-triazol-3-yl)propane) are reported in detail. The resulting complexes have been investigated by various means including elemental- and thermogravimetric analysis, IR- and electron transition spectroscopy. The structure of the Tb complex was determined by single-crystal X-ray crystallography: Tb is eight-coordinate, and L acting only as a tetradentate chelate together with two bidentate acac ligands. Photo-physical studies of the complexes were carried out. The Tb(III) and Eu(III) complexes show strong emissions both in soid state and solution. The intensity of the luminescence of Dy(III) and Sm(III) are relatively weak. The factors determining the intensity of the photoluminescence are discussed.
en
dc.language.iso
en
-
dc.publisher
ELSEVIER SCIENCE SA
-
dc.relation.ispartof
Inorganica Chimica Acta
-
dc.subject
Inorganic Chemistry
-
dc.subject
luminescence
-
dc.subject
Physical and Theoretical Chemistry
-
dc.subject
Materials Chemistry
-
dc.subject
2
-
dc.subject
1
-
dc.subject
Ln complex
-
dc.subject
4-triazole derivatives
-
dc.subject
X-ray study
-
dc.title
Synthesis, structure and luminescence studies of Eu(III), Tb(III), Sm(III), Dy(III) cationic complexes with acetylacetone and bis(5-(pyridine-2-yl)-1,2,4-triazol-3-yl)propane
en
dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
279
-
dc.description.endpage
284
-
dc.type.category
Original Research Article
-
tuw.container.volume
406
-
tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
-
tuw.researchTopic.id
M7
-
tuw.researchTopic.name
Special and Engineering Materials
-
tuw.researchTopic.value
100
-
dcterms.isPartOf.title
Inorganica Chimica Acta
-
tuw.publication.orgunit
E163-01-2 - Forschungsgruppe Koordinationschemie und bio-anorganische Chemie