The final publication is available at <a href="https://doi.org/10.1039/C4DT01933D">https://doi.org/10.1039/C4DT01933D</a>.
-
dc.description.abstract
Treatment of anhydrous FeCl2 with 2 equiv. of the pincer ligand PNP-Ph afforded the diamagnetic cationic octahedral complex [Fe(κ3-P,N,P-PNP)(κ2-P,N-PNP)Cl]+ featuring a κ2-P,N-bound PNP ligand. Preliminary reactivity studies revealed that the κ2-P,N-bound PNP ligand is labile reacting with CO to afford trans-[Fe(PNP-Ph)(CO)2Cl]+.
en
dc.description.sponsorship
Austrian Science Funds (FWF)
-
dc.description.sponsorship
Fundação para a Ciência e Tecnologia, Projecto Estratégico
-
dc.language
English
-
dc.language.iso
en
-
dc.publisher
Royal Society of Chemistry
-
dc.relation.ispartof
Dalton Transactions
-
dc.rights.uri
http://rightsstatements.org/vocab/InC/1.0/
-
dc.title
An iron(II) complex featuring κ3 and labile κ2-bound PNP pincer ligands - striking differences between CH2 and NH spacers
en
dc.type
Article
en
dc.type
Artikel
de
dc.rights.license
In Copyright
en
dc.rights.license
Urheberrechtsschutz
de
dc.contributor.affiliation
Instituto Superior Técnico, Portugal
-
dc.relation.grantno
P 24202-N17
-
dc.relation.grantno
Est-OE/QUI/UI0100/2013
-
dc.rights.holder
The Royal Society of Chemistry 2014
-
dc.type.category
Short/Brief/Rapid Communication
-
tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
-
tuw.relation.publisherplace
London
-
tuw.version
am
-
wb.publication.intCoWork
International Co-publication
-
dcterms.isPartOf.title
Dalton Transactions
-
tuw.publication.orgunit
E163 - Institut für Angewandte Synthesechemie
-
tuw.publisher.doi
10.1039/C4DT01933D
-
dc.identifier.eissn
1477-9234
-
dc.identifier.libraryid
AC11360216
-
dc.identifier.urn
urn:nbn:at:at-ubtuw:3-2059
-
tuw.author.orcid
0000-0002-0087-474X
-
tuw.author.orcid
0000-0001-5841-3519
-
tuw.author.orcid
0000-0003-0872-6159
-
dc.rights.identifier
In Copyright
en
dc.rights.identifier
Urheberrechtsschutz
de
wb.sci
true
-
item.fulltext
with Fulltext
-
item.grantfulltext
open
-
item.openairecristype
http://purl.org/coar/resource_type/c_6501
-
item.cerifentitytype
Publications
-
item.languageiso639-1
en
-
item.openairetype
journal article
-
item.openaccessfulltext
Open Access
-
item.mimetype
application/pdf
-
crisitem.author.dept
E163 - Institut für Angewandte Synthesechemie
-
crisitem.author.dept
E163-01-1 - Forschungsgruppe Organometallische Chemie und Katalyse
-
crisitem.author.dept
E057-04 - Fachbereich Röntgenzentrum
-
crisitem.author.dept
E164 - Institut für Chemische Technologien und Analytik
-
crisitem.author.dept
Instituto Superior Técnico
-
crisitem.author.dept
E163-01-1 - Forschungsgruppe Organometallische Chemie und Katalyse
