<div class="csl-bib-body">
<div class="csl-entry">Kapsamer, F. M., Seifried, M., Giester, G., Müller, D., Reissner, M., & Weinberger, P. (2022, September 20). <i>Synthesis and Coordination of Post-Functionalised Tris(Methylimidazolyl)-Methane Ligands</i> [Poster Presentation]. Österreichische Chemietage 2022, Wien, Austria. http://hdl.handle.net/20.500.12708/158154</div>
</div>
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/158154
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dc.description.abstract
Scorpionates are tripodal ligands with three electron pair donors, most commonly used are poly-substituted boron compounds which are know for their spin crossover behaviour in iron(II) complexes. The use of carbon as the central linker atom combines the associated upshift of the spin transition temperature towards room temperature
with possible post-functionalisation of the ligands. Our designed system consists of a hydroxy functionalised tripodal ligand with an increased steric demand due to a methyl subsitution at the N1-position. The variation of the synthetic conditions and the stoichiometry between ligand and metal during the reaction resulted in the identification of three competing coordination patterns, identical for iron(II) and cobalt(II). All coordination compounds were isolated and characterised with regards to their magnetic, spectroscopic and structural features, as well as cyclic voltammetry measurements.
en
dc.description.sponsorship
Fonds zur Förderung der wissenschaftlichen Forschung (FWF)
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dc.language.iso
en
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dc.subject
scorpionate ligands
en
dc.subject
imidazole
en
dc.subject
Fe(II) spin crossover
en
dc.title
Synthesis and Coordination of Post-Functionalised Tris(Methylimidazolyl)-Methane Ligands
en
dc.type
Presentation
en
dc.type
Vortrag
de
dc.contributor.affiliation
University of Vienna, Austria
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dc.relation.grantno
P31076-N28
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dc.type.category
Poster Presentation
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tuw.project.title
Design von SCO-Liganden mit Azolen und Gruppe 14 Elementen
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tuw.researchinfrastructure
Röntgenzentrum
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tuw.researchTopic.id
M8
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tuw.researchTopic.name
Structure-Property Relationsship
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tuw.researchTopic.value
100
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tuw.publication.orgunit
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie
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tuw.publication.orgunit
E138 - Institut für Festkörperphysik
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tuw.author.orcid
0000-0002-3883-4188
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tuw.author.orcid
0000-0003-4172-6193
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tuw.event.name
Österreichische Chemietage 2022
de
tuw.event.startdate
20-09-2022
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tuw.event.enddate
22-09-2022
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tuw.event.online
On Site
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tuw.event.type
Event for scientific audience
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tuw.event.place
Wien
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tuw.event.country
AT
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tuw.event.institution
GÖCH/TU Wien
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tuw.event.presenter
Kapsamer, Frieda Maria
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tuw.event.track
Multi Track
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wb.sciencebranch
Chemie
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wb.sciencebranch.oefos
1040
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wb.sciencebranch.value
100
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item.languageiso639-1
en
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item.openairetype
conference poster not in proceedings
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item.grantfulltext
none
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item.fulltext
no Fulltext
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item.cerifentitytype
Publications
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item.openairecristype
http://purl.org/coar/resource_type/c_18co
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crisitem.author.dept
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie
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crisitem.author.dept
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie
-
crisitem.author.dept
E163-01-3 - Forschungsgruppe Magneto- und Thermochemie
-
crisitem.author.dept
E138 - Institut für Festkörperphysik
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crisitem.author.dept
E163-01 - Forschungsbereich Anorganische Chemie
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crisitem.author.orcid
0000-0003-4172-6193
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crisitem.author.parentorg
E163-01 - Forschungsbereich Anorganische Chemie
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crisitem.author.parentorg
E163-01 - Forschungsbereich Anorganische Chemie
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crisitem.author.parentorg
E163-01 - Forschungsbereich Anorganische Chemie
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crisitem.author.parentorg
E130 - Fakultät für Physik
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crisitem.author.parentorg
E163 - Institut für Angewandte Synthesechemie
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crisitem.project.funder
FWF Fonds zur Förderung der wissenschaftlichen Forschung (FWF)
