<div class="csl-bib-body">
<div class="csl-entry">Bendova, M., Puchberger, M., Pabisch, S., Peterlik, H., & Schubert, U. (2010). Studies on the Formation of CdS Nanoparticles from Solutions of (NMe₄)₄[Cd₁₀S₄(SPh)₁₆]. <i>European Journal of Inorganic Chemistry</i>, <i>2010</i>(15), 2266–2275. https://doi.org/10.1002/ejic.201000080</div>
</div>
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dc.identifier.issn
1434-1948
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/166866
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dc.description.abstract
The stepwise cluster growth, and formation of CdS nanoparticles from solutions of (NMe₄)₄[Cd₁₀S₄(SPh)₁₆] in dimethyl sulfoxide (DMSO), dimethylformamide (DMF) and acetonitrile was investigated. Cluster growth is fast in DMSO and DMF at room temperature, and slow in acetonitrile at elevated temperatures. Larger sulfide clusters (initially Cd₃₂, then Cd₅₄) are initially formed, which upon further growth eventually give rise to CdS nanoparticles. Strong evidence was found that the byproduct formed during the reaction in DMSO is mononuclear [Cd(SPh)ₓ(DMSO)ᵧ]⁽²⁻ˣ⁾(x~3).
en
dc.description.sponsorship
Fonds zur Förderung der wissenschaftlichen Forschung (FWF)
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dc.language.iso
en
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dc.publisher
WILEY-V C H VERLAG GMBH
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dc.relation.ispartof
European Journal of Inorganic Chemistry
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dc.subject
Inorganic Chemistry
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dc.title
Studies on the Formation of CdS Nanoparticles from Solutions of (NMe₄)₄[Cd₁₀S₄(SPh)₁₆]
