<div class="csl-bib-body">
<div class="csl-entry">Nesterova, O. V., Petrusenko, S. R., Nesterov, D. S., Kokozay, V. N., Skelton, B. W., Jezierska, J., Linert, W., & Ozarowski, A. (2010). A Cu<sup>I</sup><sup>I</sup>Ni<sup>I</sup><sup>I</sup> Complex with Ethylenediamine: Crystal Structure and Ferromagnetic Behaviour of an Aqua-Bridged Heterometallic Chain Containing Ambidentate Ni(OAc)₄<sup>2</sup><sup>−</sup> Blocks. <i>European Journal of Inorganic Chemistry</i>, <i>2010</i>(22), 3529–3535. https://doi.org/10.1002/ejic.201000212</div>
</div>
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dc.identifier.issn
1434-1948
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/166970
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dc.description.abstract
A one-pot reaction of copper powder and nickel and ammo- nium acetates in a CH3OH solution of ethylenediamine (en) yields a unique 1D aqua-bridged polymer [Cu(en)2(μ2-H2O)2- Ni(OAc)4]n·4nH2O (1) with an ambidentate Ni(OAc)42- frag- ment that has not been previously characterized. The basic structural motif of 1 contains a previously unreported hetero- metallic M(μ2-H2O)M aqua-bridge chain with alternating metal atoms. A complex system of N/O-H···O hydrogen bonds strengthens the polymeric chains and links them into a supramolecular three-dimensional network. Variable-tem- perature magnetic susceptibility measurements of 1 revealed a weak ferromagnetic coupling (J = 1.1 cm-1) between the paramagnetic copper(II) and nickel(II) ions, which is trans- mitted through the oxygen bridges.
A CuᴵᴵNiᴵᴵ Complex with Ethylenediamine: Crystal Structure and Ferromagnetic Behaviour of an Aqua-Bridged Heterometallic Chain Containing Ambidentate Ni(OAc)₄²⁻ Blocks
en
dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
3529
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dc.description.endpage
3535
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dc.type.category
Original Research Article
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tuw.container.volume
2010
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tuw.container.issue
22
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tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
-
tuw.researchTopic.id
M2
-
tuw.researchTopic.name
Materials Characterization
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tuw.researchTopic.value
100
-
dcterms.isPartOf.title
European Journal of Inorganic Chemistry
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tuw.publication.orgunit
E163-01-2 - Forschungsgruppe Koordinationschemie und bio-anorganische Chemie
