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<div class="csl-entry">Bendova, M., Puchberger, M., & Schubert, U. (2010). Characterization of “Cd₁₀S₄(SPh)₁₂” , the Thermal Decomposition Product of (NMe₄)₄[Cd₁₀S₄(SPh)₁₆]: Synthesis of a Neutral Cd₅₄ Sulfide Cluster and of a Polymeric Chain of Thiolate-Bridged Cd₁₇ Sulfide Clusters. <i>European Journal of Inorganic Chemistry</i>, <i>2010</i>(21), 3299–3306. https://doi.org/10.1002/ejic.201000454</div>
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dc.identifier.issn
1434-1948
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/167008
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dc.description.abstract
Contrary to claims in the literature that a cluster of the composition of Cd₁₀S₄(SPh)₁₂ was formed by thermal treatment of (NMe₄)₄[Cd₁₀S₄(SPh)₁₆], experimental evidence was gathered that the core structure of the cluster is not exclusively retained and other CdS species are also formed. When Cd₁₀S₄(SPh)₁₂ was treated with PhSH/NEt₃ only a part of the material was converted into (NHEt₃)₄[Cd₁₀S₄(SPh)₁₆]. From solutions of Cd₁₀S₄(SPh)₁₂ in strongly coordinating solvents the new neutral CdS clusters Cd₅₄S₂₈(SPh)₅₂Lₓ (L = pyridine, DMSO or DMF) and [Cd₁₇S₄(SPh)₂₆py] were crystallized. The latter forms polymeric chains of phenylthiolate-bridged Cd₁₇ units.
en
dc.description.sponsorship
Fonds zur Förderung der wissenschaftlichen Forschung (FWF)
Characterization of "Cd₁₀S₄(SPh)₁₂" , the Thermal Decomposition Product of (NMe₄)₄[Cd₁₀S₄(SPh)₁₆]: Synthesis of a Neutral Cd₅₄ Sulfide Cluster and of a Polymeric Chain of Thiolate-Bridged Cd₁₇ Sulfide Clusters
