<div class="csl-bib-body">
<div class="csl-entry">Scheffler, D., Grothe, H., Willner, H., Frenzel, A., & Zetzsch, C. (1997). Properties of Pure Nitryl Bromide. Thermal Behavior, UV/Vis and FTIR Spectra, and Photoisomerisation to trans-BrONO in an Argon Matrix. <i>Inorganic Chemistry</i>, <i>36</i>(3), 335–338. https://doi.org/10.1021/ic9606946</div>
</div>
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dc.identifier.issn
0020-1669
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/175318
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dc.description.abstract
BrNO₂ is produced by the heterogeneous reaction of ClNO₂, highly diluted in He, with an aqueous bromide solution and subsequent trapping at -155 °C. The crude product is purified by trap to trap condensation and fractional sublimation in vacuo. At 300 K and a pressure of 1 mbar, a half-life of about 1 h is observed. The decomposition produces Br₂ and NO₂. The UV/vis and IR absorption cross sections of gaseous BrNO₂ are determined in the ranges 185-600 nm and 2000-400 cm⁻¹, respectively. Irradiation of matrix-isolated BrNO₂ with visible light causes nearly quantitative isomerization to trans-BrONO, while ClNO₂ is converted by UV light into a mixture of cis- and trans-ClONO. It is possible to assign all fundamentals of BrNO₂ and trans-BrONO by comparison to the respective band position of the analogous molecules XNO₂ and XONO (X = Cl, F).
en
dc.language.iso
en
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dc.publisher
American Chemical Society
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dc.relation.ispartof
Inorganic Chemistry
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dc.subject
Inorganic Chemistry
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dc.subject
Physical and Theoretical Chemistry
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dc.title
Properties of Pure Nitryl Bromide. Thermal Behavior, UV/Vis and FTIR Spectra, and Photoisomerisation to trans-BrONO in an Argon Matrix
en
dc.type
Artikel
de
dc.type
Article
en
dc.description.startpage
335
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dc.description.endpage
338
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dc.type.category
Original Research Article
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tuw.container.volume
36
-
tuw.container.issue
3
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tuw.journal.peerreviewed
true
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tuw.peerreviewed
true
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tuw.researchTopic.id
E4
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tuw.researchTopic.name
Environmental Monitoring and Climate Adaptation
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tuw.researchTopic.value
100
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dcterms.isPartOf.title
Inorganic Chemistry
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tuw.publication.orgunit
E165-01-5 - Forschungsgruppe Physikalische Chemie von Aerosolpartikeln
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tuw.publisher.doi
10.1021/ic9606946
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dc.identifier.eissn
1520-510X
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dc.description.numberOfPages
4
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wb.sci
true
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wb.sciencebranch
Chemie
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wb.sciencebranch.oefos
13
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wb.facultyfocus
Sustainability, Energy, Environment
de
wb.facultyfocus
Sustainability, Energy, Environment
en
wb.facultyfocus.faculty
E150
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no Fulltext
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Publications
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Publications
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item.languageiso639-1
en
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Artikel
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Article
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http://purl.org/coar/resource_type/c_18cf
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http://purl.org/coar/resource_type/c_18cf
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none
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crisitem.author.dept
E165-01-5 - Forschungsgruppe Physikalische Chemie von Aerosolpartikeln