<div class="csl-bib-body">
<div class="csl-entry">Stagel, K., Pálvölgyi, Á. M., Delmas, C., Schnürch, M., & Schröder, K. (2023). Supported Ionic Liquid Phase (SILP) Allylic Alkylation of Amines in Continuous Flow. <i>ChemCatChem</i>, Article e202300381. https://doi.org/10.1002/cctc.202300381</div>
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dc.identifier.issn
1867-3880
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/186960
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dc.description.abstract
We present the use of Pd-complex-containing supported ionic liquid phases (SILPs) as a novel approach for continuous-flow allylic alkylation of N-nucleophiles. This immobilization strategy gave simple access to air-tolerating catalyst frameworks, providing rapid and convenient access to various achiral and chiral N-allylation products. Under optimized conditions, the flow-reaction could be maintained for 3.5 hours with constant product output; meanwhile, only a marginal 0.7 wt % of ionic liquid leaching and no detectable palladium-complex leaching could be observed.
en
dc.language.iso
en
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dc.publisher
WILEY-V C H VERLAG GMBH
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dc.relation.ispartof
ChemCatChem
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dc.subject
chiral catalyst
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dc.subject
continuous flow
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dc.subject
ionic liquid
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dc.subject
SILP
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dc.subject
Tsuji-Trost reaction
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dc.title
Supported Ionic Liquid Phase (SILP) Allylic Alkylation of Amines in Continuous Flow
