<div class="csl-bib-body">
<div class="csl-entry">Kratena, N., Weil, M., & Gärtner, P. (2023). A biomimetic approach for the concise total synthesis of greenwaylactams A-C. <i>Organic and Biomolecular Chemistry</i>, <i>21</i>(31), 6317–6319. https://doi.org/10.1039/d3ob01001e</div>
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dc.identifier.issn
1477-0520
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/190512
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dc.description.abstract
A concise, racemic total synthesis of three sesquiterpenoid alkaloids (greenwaylactams A-C) exhibiting an unprecedented 8-membered benzolactam is disclosed. Key transformations of this work include the ring expansion through cleavage of an indole via Witkop oxidation, as well as an HFIP mediated cationic cyclisation to build up the pentacyclic carbon skeleton.
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dc.language.iso
en
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dc.publisher
ROYAL SOC CHEMISTRY
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dc.relation.ispartof
Organic and Biomolecular Chemistry
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dc.rights.uri
http://creativecommons.org/licenses/by/3.0/
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dc.subject
racemuc total synthesis
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dc.subject
sesquiterpenoid alkaloids
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dc.subject
Witkop oxidation
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dc.title
A biomimetic approach for the concise total synthesis of greenwaylactams A-C
