<div class="csl-bib-body">
<div class="csl-entry">Bernabé Vírseda, I., Siddiqui, S. A., Prado‐Roller, A., Eisterer, M., & Shiozawa, H. (2023). A Novel Molecular Assembly of a Cobalt-Sulfate Coordination Polymer and Melamine: A Manifestation of Magnetic Anisotropy. <i>ACS Omega</i>, <i>8</i>(3), 3493–3500. https://doi.org/10.1021/acsomega.2c07556</div>
</div>
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dc.identifier.issn
2470-1343
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/191362
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dc.description.abstract
A novel molecular assembly of a cobalt-sulfate coordination polymer and melamine is synthesized under acidic conditions. Bar-shaped pink monocrystals as long as 1 mm are found to align along magnetic field lines in the proximity of a strong magnet. Magnetometry shows no hysteresis at temperatures down to 2 K but instead magnetic anisotropy and antiferromagnetic coupling. X-ray diffraction on a single crystal reveals that the cobalt-sulfate chains are along the shortest lattice vector or the crystal's long axis. The crystal alignment along the magnetic flux can be attributed to single-ion anisotropy that results in longitudinal antiferromagnetic coupling along the chain. Both structurally and magnetically isotropic crystals of metal-organic hybrid materials can be highly useful as elemental components in magneto-optics.
en
dc.language.iso
en
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dc.publisher
AMER CHEMICAL SOC
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dc.relation.ispartof
ACS Omega
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dc.subject
cobalt−sulfate coordination polymer
en
dc.subject
melamine
en
dc.subject
Magnetic Anisotropy
en
dc.title
A Novel Molecular Assembly of a Cobalt-Sulfate Coordination Polymer and Melamine: A Manifestation of Magnetic Anisotropy
en
dc.type
Article
en
dc.type
Artikel
de
dc.identifier.pmid
36713744
-
dc.contributor.affiliation
Politechnic University of Madrid
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dc.contributor.affiliation
University of Vienna, Austria
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dc.description.startpage
3493
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dc.description.endpage
3500
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dc.type.category
Original Research Article
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tuw.container.volume
8
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tuw.container.issue
3
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tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
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wb.publication.intCoWork
International Co-publication
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tuw.researchTopic.id
M2
-
tuw.researchTopic.id
M4
-
tuw.researchTopic.name
Materials Characterization
-
tuw.researchTopic.name
Non-metallic Materials
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tuw.researchTopic.value
50
-
tuw.researchTopic.value
50
-
dcterms.isPartOf.title
ACS Omega
-
tuw.publication.orgunit
E141-06 - Forschungsbereich Low Temperature Physics and Superconductivity
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tuw.publisher.doi
10.1021/acsomega.2c07556
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dc.date.onlinefirst
2023
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dc.identifier.eissn
2470-1343
-
dc.description.numberOfPages
8
-
tuw.author.orcid
0000-0001-9795-8466
-
tuw.author.orcid
0000-0002-7160-7331
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tuw.author.orcid
0000-0003-0603-2508
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wb.sci
true
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wb.sciencebranch
Chemie
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wb.sciencebranch
Physik, Astronomie
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1040
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wb.sciencebranch.oefos
1030
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50
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50
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Publications
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none
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no Fulltext
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item.languageiso639-1
en
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item.openairecristype
http://purl.org/coar/resource_type/c_2df8fbb1
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item.openairetype
research article
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crisitem.author.dept
Politechnic University of Madrid
-
crisitem.author.dept
University of Vienna, Austria
-
crisitem.author.dept
E141-06 - Forschungsbereich Low Temperature Physics and Superconductivity