<div class="csl-bib-body">
<div class="csl-entry">Haidinger, A., Dilly, C. I., Fischer, R. C., Svatunek, D., Uher, J. M., & Hlina, J. A. (2023). To Bond or Not to Bond: Metal-Metal Interaction in Heterobimetallic Rare-Earth Metal-Silver Complexes. <i>Inorganic Chemistry</i>, <i>62</i>(43), 17713–17720. https://doi.org/10.1021/acs.inorgchem.3c02377</div>
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dc.identifier.issn
0020-1669
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/191514
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dc.description.abstract
The reaction of 2,4-tBu2-6-(PPh2)PhOH (HOArP) with silver(I) triflate in a 3:1 molar ratio gave the mononuclear coinage metal complex (HOArP-κP)3AgIOTf (1). Treatment of HOArP with LnIII[N(SiMe3)2]3 (Ln = La, Sm, Y, Yb) in a 3:1 molar ratio yielded the mononuclear rare-earth metal complexes LnIII(OArP-κ2O,P)3 (2-Ln). The heterobimetallic rare-earth metal-silver complexes LnIII(OTf)(μ-OArP-1κ1O,2κ1P)3AgI (3-Ln) were prepared from monometallic precursors by reactions of equimolar amounts of 1 with LnIII[N(SiMe3)2]3 or 2-Ln with silver(I) triflate, respectively. The compounds were characterized by NMR, ultraviolet-visible (UV-vis), and infrared (IR) spectroscopy, single-crystal X-ray diffraction, elemental analysis, and the effective magnetic moments of the paramagnetic complexes were determined via the Evans NMR method. Computational studies were conducted on 3-La and 3-Y.
en
dc.description.sponsorship
FWF - Österr. Wissenschaftsfonds
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dc.language.iso
en
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dc.publisher
AMER CHEMICAL SOC
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dc.relation.ispartof
Inorganic Chemistry
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dc.subject
Aromatic compounds
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dc.subject
Hydrocarbons
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dc.subject
ligands
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dc.subject
Metals
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dc.subject
Silver
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dc.title
To Bond or Not to Bond: Metal-Metal Interaction in Heterobimetallic Rare-Earth Metal-Silver Complexes
