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Year of Publication
DC Field
Value
Language
dc.contributor.author
Stadler, Benedek
-
dc.contributor.author
Gorgas, Nikolaus
-
dc.contributor.author
White, Andrew
-
dc.contributor.author
Crimmin, Mark
-
dc.date.accessioned
2024-01-11T11:16:52Z
-
dc.date.available
2024-01-11T11:16:52Z
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dc.date.issued
2023-04-11
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dc.identifier.citation
<div class="csl-bib-body"> <div class="csl-entry">Stadler, B., Gorgas, N., White, A., & Crimmin, M. (2023). Double Deprotonation of CH₃CN by an Iron-Aluminium Complex. <i>ANGEWANDTE CHEMIE-INTERNATIONAL EDITION</i>, <i>62</i>(16), Article e202219212. https://doi.org/10.1002/anie.202219212</div> </div>
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dc.identifier.issn
1433-7851
-
dc.identifier.uri
http://hdl.handle.net/20.500.12708/191583
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dc.description.abstract
Hereinwe presentthe firstdoubledeprotona-tionof acetonitrile(CH3CN)usingtwo equivalentsof abimetalliciron-aluminiumcomplex.Theproductsof thisreactioncontainan exceedingsimpleyet rare[CHCN]2 dianionmoietythatbridgestwometalfragments.DFTcalculationssuggestthatthebondingto themetalcentresoccursthroughheavilypolarisedcovalentinter-actions.Mechanisticstudiesrevealthe intermediacyof amonomeric[CH2CN] complex,whichhas beencharac-terisedin situ.Ourfindingsprovidean importantexamplein whicha bimetallicmetalcomplexachievesanewtypeof reactivitynot previouslyencounteredwithmonometalliccounterparts.[1,2]Theisolationof a[CHCN]2 dianionthroughsimpledeprotonationofCH3CNalsooffersthepossibilityof establishingabroaderchemistryof this motif.
en
dc.description.sponsorship
FWF - Österr. Wissenschaftsfonds
-
dc.language.iso
en
-
dc.publisher
WILEY-V C H VERLAG GMBH
-
dc.relation.ispartof
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
-
dc.subject
Aluminium
en
dc.subject
CH Activation
en
dc.subject
Dianions
en
dc.subject
Iron
en
dc.subject
Nitriles
en
dc.title
Double Deprotonation of CH₃CN by an Iron-Aluminium Complex
en
dc.type
Article
en
dc.type
Artikel
de
dc.contributor.affiliation
Imperial College London
-
dc.contributor.affiliation
Illinois State Archaeological Survey
-
dc.contributor.affiliation
Imperial College London
-
dc.relation.grantno
J 4399-N
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dc.type.category
Original Research Article
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tuw.container.volume
62
-
tuw.container.issue
16
-
tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
-
wb.publication.intCoWork
International Co-publication
-
tuw.project.title
Eisen Katalysierte Wasserstoff Isotopen Markierung
-
tuw.researchinfrastructure
Vienna Scientific Cluster
-
tuw.researchTopic.id
E6
-
tuw.researchTopic.name
Sustainable Production and Technologies
-
tuw.researchTopic.value
100
-
dcterms.isPartOf.title
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
-
tuw.publication.orgunit
E163-01-1 - Forschungsgruppe Organometallische Chemie und Katalyse
-
tuw.publisher.doi
10.1002/anie.202219212
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dc.date.onlinefirst
2023-02-17
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dc.identifier.articleid
e202219212
-
dc.identifier.eissn
1521-3773
-
dc.description.numberOfPages
5
-
tuw.author.orcid
0000-0002-7423-7524
-
tuw.author.orcid
0000-0002-9859-0947
-
tuw.author.orcid
0000-0002-9339-9182
-
dc.description.sponsorshipexternal
FluoroCycle
-
dc.relation.grantnoexternal
101001071
-
wb.sci
true
-
wb.sciencebranch
Chemie
-
wb.sciencebranch.oefos
1040
-
wb.sciencebranch.value
100
-
item.cerifentitytype
Publications
-
item.grantfulltext
none
-
item.fulltext
no Fulltext
-
item.languageiso639-1
en
-
item.openairecristype
http://purl.org/coar/resource_type/c_2df8fbb1
-
item.openairetype
research article
-
crisitem.project.funder
FWF - Österr. Wissenschaftsfonds
-
crisitem.project.grantno
J 4399-N
-
crisitem.author.dept
Imperial College London
-
crisitem.author.dept
E163-01-1 - Forschungsgruppe Organometallische Chemie und Katalyse
-
crisitem.author.dept
Illinois State Archaeological Survey
-
crisitem.author.dept
Imperial College London
-
crisitem.author.orcid
0000-0002-7423-7524
-
crisitem.author.orcid
0000-0002-9859-0947
-
crisitem.author.orcid
0000-0002-9339-9182
-
crisitem.author.parentorg
E163-01 - Forschungsbereich Anorganische Chemie
-
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