<div class="csl-bib-body">
<div class="csl-entry">Schmid, B., Koutná, N., Hahn, R., Wojcik, T., Polcik, P., & Mayrhofer, P. H. (2023). Development of TaC-based transition metal carbide superlattices via compound target magnetron sputtering. <i>INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS</i>, <i>113</i>, Article 106165. https://doi.org/10.1016/j.ijrmhm.2023.106165</div>
</div>
-
dc.identifier.issn
0263-4368
-
dc.identifier.uri
http://hdl.handle.net/20.500.12708/191721
-
dc.description.abstract
Transition metal carbides belong to ultra-high temperature ceramics and are particularly valued for their high thermal and mechanical stability as well as melting points of even above 4000 °C. However, a considerable limitation of these materials is their high inherent brittleness. Inspired by the success of nanolayered superlattice architecture—shown to enhance both hardness and toughness of transition metal (TM) nitrides—we developed superlattice films with TM carbides. Among these, density functional theory calculations suggest TaC/HfC and TiC/TaC to have a similar shear modulus mismatch of 23 and 19 GPa, but a different lattice parameter mismatch of 4.2 and 2.4%, respectively. Detailed transmission electron microscopy and X-ray diffraction show a pronounced superlattice structure for TiC/TaC with nominal bilayer periods Λnom of 2, 6, and 10 nm. Contrary, the TaC/HfC showed a more solid solution like characteristic for Λnom = 2 nm, and a clear superlattice structure for Λnom = 6 and 10 nmjap. While the hardness of the TaC/HfC coatings is between those of their constituents TaC (33.3 ± 1.9 GPa) and HfC (37.4 ± 3.2 GPa), the TiC/TaC superlattices outperform their constituents and clearly show a superlattice-effect with a peak of 44.1 ± 3.4 GPa at Λnom = 2 nm (TiC has 37.6 ± 3.1 GPa). Also the qualitative fracture behavior investigation with 450-mN-loaded cube corner indentation yield the TiC/TaC superlattices to be superior to the TaC/HfC as well as the monolithically prepared TiC, TaC, and HfC coatings.
en
dc.language.iso
en
-
dc.publisher
ELSEVIER SCI LTD
-
dc.relation.ispartof
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS
-
dc.rights.uri
http://creativecommons.org/licenses/by-nc-nd/4.0/
-
dc.subject
Carbide
en
dc.subject
Hardness
en
dc.subject
Superlattice
en
dc.subject
Tantalum
en
dc.subject
Transition metal
en
dc.title
Development of TaC-based transition metal carbide superlattices via compound target magnetron sputtering
en
dc.type
Article
en
dc.type
Artikel
de
dc.rights.license
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
en
dc.rights.license
Creative Commons Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International