<div class="csl-bib-body">
<div class="csl-entry">Klampfl, B., Wöhrer, S., Kahr, J., & Rosenberg, E. E. (2023, April 11). <i>Fast Gas Chromatography with development of a negative-thermal gradient GC for the study of volatile products formed in lithium-ion batteries</i> [Poster Presentation]. ANAKON 2023, Wien, Austria. http://hdl.handle.net/20.500.12708/193862</div>
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/193862
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dc.description.abstract
Improvements to the longevity, energy-density, cost-efficiency and charging times are crucial aspects for the viability of lithium-ion batteries. Research on LIBs aims at optimizing electrolyte composition and establishing a deeper understanding of their degradation and stabilization mechanisms. To investigate the degradation and aging mechanisms of the electrolyte in-situ, a real-time- (operando) method is required. Highly time-resolved analysis of the gas species that are formed during the use of LIBs is crucial to understand the dynamics of the process. To achieve this, a GC/MS system equipped with a fast-measuring system to enable short injection intervals is employed. The long cycle times of conventional temperature programmed gas chromatography prompted us to look for a different approach.
Directly heated short columns allowing for rapid heating rates (> 1400 K min-1) appeared to be a suitable solution. Negative thermal gradients were investigated for their suitability to improve separation efficiency. For this purpose, different setups were designed and tested on their ability to enable fast separations.
We report here two experimental setups capable of producing spatially resolved temperature gradients along a GC column. The systems achieved rapid changes in the shape of their gradients and enabled fast separations of analytes with high volatility range. It was shown that base-line separated measurements of a C8-C20 n-alkane standard could be realised in less than 30 seconds for both systems. Both systems require little resources in comparison to conventional gas chromatography in terms of electricity and carrier gas consumption. These aspects make this technology a viable asset for more sustainable analytical processes.
• Fast negative-thermal gradient GC
• Short separation cycles for in-situ and on-line analysis
• Sustainable gas chromatography
Acknowledgements
Financial support of this work in the frame of the FFG (Austrian Research Promotion Agency) Project “OPERION” (proj. no. 879613) is gratefully acknowledged.
en
dc.language.iso
en
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dc.subject
fast gas chromatography
en
dc.subject
process analysis
en
dc.subject
lithium ion battery
en
dc.subject
electrolyte decomposition
en
dc.title
Fast Gas Chromatography with development of a negative-thermal gradient GC for the study of volatile products formed in lithium-ion batteries
en
dc.type
Presentation
en
dc.type
Vortrag
de
dc.contributor.affiliation
Austrian Institute of Technology, Austria
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dc.rights.holder
(c) The Authors 2023.
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dc.type.category
Poster Presentation
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tuw.researchTopic.id
E2
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tuw.researchTopic.name
Sustainable and Low Emission Mobility
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tuw.researchTopic.value
100
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tuw.publication.orgunit
E164-01-2 - Forschungsgruppe Oberflächen-, Spurenanalytik und Chemometrie
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tuw.author.orcid
0000-0001-8355-8533
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tuw.event.name
ANAKON 2023
en
tuw.event.startdate
11-04-2023
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tuw.event.enddate
14-04-2023
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tuw.event.online
On Site
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tuw.event.type
Event for scientific audience
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tuw.event.place
Wien
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tuw.event.country
AT
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tuw.event.institution
TU Wien
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tuw.event.presenter
Klampfl, Bernhard
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tuw.event.track
Multi Track
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wb.sciencebranch
Chemie
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wb.sciencebranch.oefos
1040
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wb.sciencebranch.value
100
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item.openairecristype
http://purl.org/coar/resource_type/c_18co
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item.languageiso639-1
en
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item.fulltext
no Fulltext
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item.grantfulltext
none
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item.openairetype
conference poster not in proceedings
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item.cerifentitytype
Publications
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crisitem.author.dept
E164-01-2 - Forschungsgruppe Oberflächen-, Spurenanalytik und Chemometrie
-
crisitem.author.dept
E164-02-1 - Forschungsgruppe Prozessanalytik
-
crisitem.author.dept
Austrian Institute of Technology
-
crisitem.author.dept
E164-01-2 - Forschungsgruppe Oberflächen-, Spurenanalytik und Chemometrie
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crisitem.author.orcid
0009-0006-9836-118X
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crisitem.author.parentorg
E164-01 - Forschungsbereich Imaging und Instrumentelle Analytische Chemie
-
crisitem.author.parentorg
E164-02 - Forschungsbereich Umwelt-, Prozessanalytik und Sensoren
-
crisitem.author.parentorg
E164-01 - Forschungsbereich Imaging und Instrumentelle Analytische Chemie
