<div class="csl-bib-body">
<div class="csl-entry">Gusev, A., Braga, E., Kaleukh, A., Baevsky, M., Kiskin, M., & Linert, W. (2024). Multistimuli Luminescence and Anthelmintic Activity of Zn(II) Complexes Based on 1H-Benzimidazole-2-yl Hydrazone Ligands. <i>Inorganics</i>, <i>12</i>(9), Article 256. https://doi.org/10.3390/inorganics12090256</div>
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dc.identifier.issn
2304-6740
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/201168
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dc.description.abstract
Three novel Zn(II) mononuclear complexes with the general formula ZnL₂Cl₂ (L = 2-(4-R-phenylmethylene)benzimidazol-2-hydrazines; R-H (1), R-CH₃ (2), and R-OCH₃ (3)) were synthesized and fully characterized by various means. These complexes demonstrate excitation-dependent emission, which is detected by a change in the emission color (from blue to green) upon an increase in the excitation wavelength. Moreover complex 1 shows reversible mechanochromic luminescence behavior due to the reversible loss of solvated methanol molecules upon the intense grinding of crystals. In addition, 1 exhibits vapochromic properties, which originate from the adsorption methanol vapor on the crystal surface. The strengthening of anthelmintic activity at the transition from free hydrazones to zinc-based complexes is shown.
en
dc.language.iso
en
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dc.publisher
MDPI
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dc.relation.ispartof
Inorganics
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dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
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dc.subject
benzimidazoles
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dc.subject
hydrazones
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dc.subject
zinc(II) complexes
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dc.subject
photoluminescence
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dc.subject
biological activity
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dc.title
Multistimuli Luminescence and Anthelmintic Activity of Zn(II) Complexes Based on 1H-Benzimidazole-2-yl Hydrazone Ligands
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dc.type
Article
en
dc.type
Artikel
de
dc.rights.license
Creative Commons Namensnennung 4.0 International
de
dc.rights.license
Creative Commons Attribution 4.0 International
en
dc.contributor.affiliation
V.I. Vernadsky Crimean Federal University, Ukraine
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dc.contributor.affiliation
V.I. Vernadsky Crimean Federal University, Ukraine
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dc.contributor.affiliation
V.I. Vernadsky Crimean Federal University, Ukraine
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dc.contributor.affiliation
V.I. Vernadsky Crimean Federal University, Ukraine
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dc.contributor.affiliation
Russian Academy of Sciences, Russian Federation (the)