<div class="csl-bib-body">
<div class="csl-entry">Bonta, M., Anderl, T., Cognigni, A., Hejazifar, M., Schröder, K., & Limbeck, A. (2016). Determination of residual chloride content in ionic liquids using LA-ICP-MS. <i>RSC Advances</i>, <i>6</i>, 90273–90279. https://doi.org/10.1039/C6RA21203D</div>
</div>
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dc.identifier.issn
2046-2069
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/20232
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dc.description.abstract
Nowadays, ionic liquids (ILs) are used in a wide range of applications. Their exceptional chemical and physical properties, sustainability of use and the possibility of easy recycling are attractive aspects promoting the acceptance of ILs also for commercial applications. While synthesis is in most cases simple and straightforward, purification of the reaction products might pose a number of problems. Due to the major influence of inorganic contaminations from the synthesis process, thorough monitoring of impurities is required. However, the unusual properties of ILs create some problems for conventional chemical analysis. In this work, a dried droplet approach with subsequent LA-ICP-MS sampling will be used for the analysis of chloride in ILs – a by-product from the synthesis procedure. Dried droplet application onto pre-cut filter paper disks allows the analysis of hydrophilic as well as hydrophobic ILs with calibration from dried aqueous standards for signal quantification. The approach is applied on two types of alkylimidazolium ILs, underlining the versatility of the sample preparation and measurement approach. Compared to commonly used analysis techniques for chloride in ILs, the presented approach is simple, fast, and does not require harmful reagents. Different internal standardization strategies were investigated during this study. With a reproducibility of below 2% relative standard deviation and limits of detection of 0.09 mg g−1 for chloride in ILs, the presented approach was showed to be fit for the purpose of routine analyses and reaction monitoring. If necessary, the approach can be extended to other analytes of interest in the field of the synthetic chemistry of ILs.
en
dc.language.iso
en
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dc.publisher
ROYAL SOC CHEMISTRY
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dc.relation.ispartof
RSC Advances
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dc.rights.uri
http://creativecommons.org/licenses/by/3.0/
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dc.subject
LA-ICP-MS
en
dc.title
Determination of residual chloride content in ionic liquids using LA-ICP-MS
en
dc.type
Article
en
dc.type
Artikel
de
dc.rights.license
Creative Commons Attribution 3.0 Unported
en
dc.rights.license
Creative Commons Namensnennung 3.0 Unported
de
dc.description.startpage
90273
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dc.description.endpage
90279
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dcterms.dateSubmitted
2016-08-23
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dc.type.category
Original Research Article
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tuw.container.volume
6
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tuw.journal.peerreviewed
true
-
tuw.peerreviewed
true
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dcterms.isPartOf.title
RSC Advances
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tuw.publication.orgunit
E164 - Institut für Chemische Technologien und Analytik
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tuw.publication.orgunit
E163 - Institut für Angewandte Synthesechemie
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tuw.publisher.doi
10.1039/C6RA21203D
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dc.identifier.eissn
2046-2069
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dc.identifier.libraryid
AC17203657
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dc.description.numberOfPages
7
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tuw.author.orcid
0000-0002-2515-9873
-
tuw.author.orcid
0000-0001-5042-2445
-
dc.rights.identifier
CC BY 3.0
en
dc.rights.identifier
CC BY 3.0
de
wb.sci
true
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item.openaccessfulltext
Open Access
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item.cerifentitytype
Publications
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item.languageiso639-1
en
-
item.openairecristype
http://purl.org/coar/resource_type/c_2df8fbb1
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item.grantfulltext
open
-
item.fulltext
with Fulltext
-
item.mimetype
application/pdf
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item.openairetype
research article
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crisitem.author.dept
E164 - Institut für Chemische Technologien und Analytik
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crisitem.author.dept
TU Wien
-
crisitem.author.dept
E163 - Institut für Angewandte Synthesechemie
-
crisitem.author.dept
E163 - Institut für Angewandte Synthesechemie
-
crisitem.author.dept
E163-03-5 - Forschungsgruppe Nachhaltige organische Synthese und Katalyse
-
crisitem.author.dept
E164-01-2 - Forschungsgruppe Oberflächen-, Spurenanalytik und Chemometrie
-
crisitem.author.orcid
0000-0002-2515-9873
-
crisitem.author.orcid
0000-0001-5042-2445
-
crisitem.author.parentorg
E150 - Fakultät für Technische Chemie
-
crisitem.author.parentorg
E150 - Fakultät für Technische Chemie
-
crisitem.author.parentorg
E150 - Fakultät für Technische Chemie
-
crisitem.author.parentorg
E163-03 - Forschungsbereich Organische und Biologische Chemie
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crisitem.author.parentorg
E164-01 - Forschungsbereich Imaging und Instrumentelle Analytische Chemie