<div class="csl-bib-body">
<div class="csl-entry">Nastran, M., Peschek, P., Walendzik, I., Rath, J., Fickl, B., Schubert, J. S., Szabo, G., Wilhelm, R. A., Schmidt, J., Eder, D., & Bayer-Skoff, B. (2024, June 24). <i>High-yield liquid phase exfoliation of graphene utilizing low boiling co-solvent solutions and ammonia</i> [Poster Presentation]. NT24, Cambridge, Boston, United States of America (the). http://hdl.handle.net/20.500.12708/203125</div>
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/203125
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dc.description.abstract
Graphene is a two-dimensional carbon material with unique chemical, electrical and mechanical properties that has a wide range of potential applications in various fields. One of the most effective methods of producing graphene is liquid phase exfoliation (LPE), in which bulk graphite is broken down into its individual layers while suspended in a suitable suspension medium ('solvent'). However, this exfoliation process can be challenging due to the complex effects of the solvent system on exfoliation, dispersibility and yield.
To overcome these challenges, and extending previous findings by Arao et al. [Carbon 118, 18–24 (2017)], we have developed a highly efficient method for exfoliation of graphite to graphene using a cosolvent system of low boiling point organic solvents in combination with water and ammonia (NH₃) as additive. Our method results in high yields of graphene and, importantly, all suspension components including the ammonia additive are also readily removable. Our work thus demonstrates a facile route to improved graphene LPE yields by introducing a very easily removable additive (NH₃) in a wide range of solvent mixtures (including low boiling point and benign mixtures), thus providing a framework for simpler, more flexible and safer 2D graphene LPE development. Such produced nanographite flakes were furthermore compared with other (nano-)carbon fillers for electrically conductive coatings with various polymer binders. The high electrical conductivity values achieved enable a wide range of applications as a lightweight, conductive coating.
en
dc.language.iso
en
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dc.subject
liquid-phase exfoliation
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dc.title
High-yield liquid phase exfoliation of graphene utilizing low boiling co-solvent solutions and ammonia
