<div class="csl-bib-body">
<div class="csl-entry">Schachamayr, D., Templ, J., Weil, M., Gärtner, P., & Enev, V. S. (2024). Construction of the Bicyclic Carbon Framework of Euphosalicin. <i>Journal of Organic Chemistry</i>, <i>89</i>(14), 10239–10257. https://doi.org/10.1021/acs.joc.4c01147</div>
</div>
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dc.identifier.issn
0022-3263
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/212503
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dc.description.abstract
Our studies toward the total synthesis of the natural product euphosalicin (1) are presented. Different approaches targeting key intermediates are described, the synthesis of which includes findings on asymmetric dihydroxylations and ring-closing enyne metatheses (RCEYM). Their connection allowed the isolation of highly advanced precursors for studies on macrocyclizations. Our efforts culminated in the preparation of the unique C11/C12 (Z) isomer of the C13 nor methyl skeleton of euphosalicin (1).
en
dc.description.sponsorship
FWF - Österr. Wissenschaftsfonds
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dc.language.iso
en
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dc.publisher
AMER CHEMICAL SOC
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dc.relation.ispartof
Journal of Organic Chemistry
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dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
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dc.subject
total synthesis
en
dc.subject
macrocyclization
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dc.subject
jatrophanes
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dc.title
Construction of the Bicyclic Carbon Framework of Euphosalicin
