<div class="csl-bib-body">
<div class="csl-entry">Rabijasz, C., Weber, S., Stöger, B., & Kirchner, K. (2025). Synthesis and Application of PN-Supported Mn(I) Carbonyl Alkyl Complexes. <i>Organometallics</i>, <i>44</i>(9), 1006–1011. https://doi.org/10.1021/acs.organomet.5c00095</div>
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dc.identifier.issn
0276-7333
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/224321
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dc.description.abstract
This work comprises the synthesis and characterization of aminophosphine (PN)-derived Mn(I) carbonyl complexes and the preliminary investigation of their alkylated congeners for catalytic applications. The complexes fac-[Mn(PN)(CO)3Br] are obtained from the reaction of Mn(CO)5Br with the bidentate ligand PN = R2N(CH2)2PR'2, where R = Me, Et, and pyrrolidine and R' = Ph, iPr, and Cy. Treatment of fac-[Mn(PN)(CO)3Br] with AgOTf yields fac-[Mn(PN)(CO)3OTf]. Upon reaction of fac-[Mn(PN)(CO)3OTf] with MeLi (R' = alkyl) or MeMgCl (R' = aryl), fac-[Mn(PN)(CO)3Me] is formed. fac-[Mn(PCyNMe)(CO)3Me] and fac-[Mn(PPhNMe)(CO)3Me] are identified as the best catalysts for the dimerization of phenylacetylene and the hydroboration of 4-chlorostyrene, respectively.
en
dc.language.iso
en
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dc.publisher
AMER CHEMICAL SOC
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dc.relation.ispartof
Organometallics
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dc.subject
Manganese
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dc.subject
Alkyl Complexes
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dc.subject
Catalysis
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dc.subject
Aminophosphines
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dc.title
Synthesis and Application of PN-Supported Mn(I) Carbonyl Alkyl Complexes
