Nanometer-sized and stable thiolate-protected cobalt clusters were synthesized by a wet chemical method, leading to a pink solution with well-defined optical activity (UV-Vis) and photoluminescence (PL). The cobalt cluster core of ~1.3 nm size was metallic (as indicated by STEM, STM, XPS, HAADF-EELS) and was surrounded by a specific configuration of thiolate staples (according to Raman, FTIR, XAFS, MALDI) that is similar to that of corresponding gold clusters.
en
dc.description.sponsorship
Austrian Science Funds (FWF)
-
dc.language
English
-
dc.language.iso
en
-
dc.publisher
American Chemical Society (ACS)
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dc.relation.ispartof
Journal of Physical Chemistry C
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dc.rights.uri
http://rightsstatements.org/vocab/InC/1.0/
-
dc.subject
STM
en
dc.title
Synthesis and Properties of Monolayer Protected Cox(SC2H4Ph)m Nanoclusters
en
dc.type
Article
en
dc.type
Artikel
de
dc.rights.license
Urheberrechtsschutz
de
dc.rights.license
In Copyright
en
dc.contributor.affiliation
TU Wien, Österreich
-
dc.contributor.affiliation
Paul Scherrer Institute, Switzerland
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dc.contributor.affiliation
TU Wien, Österreich
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dc.description.startpage
10948
-
dc.description.endpage
10956
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dc.relation.grantno
F4502-N16
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dc.relation.grantno
I 1041-N28
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dc.rights.holder
2017 American Chemical Society
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dc.type.category
Original Research Article
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tuw.container.volume
121
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tuw.container.issue
20
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tuw.journal.peerreviewed
true
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tuw.peerreviewed
true
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tuw.version
am
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dcterms.isPartOf.title
Journal of Physical Chemistry C
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tuw.publication.orgunit
E165 - Institut für Materialchemie
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tuw.publisher.doi
10.1021/acs.jpcc.6b12076
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dc.identifier.eissn
1932-7455
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dc.identifier.libraryid
AC15199997
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dc.description.numberOfPages
9
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dc.identifier.urn
urn:nbn:at:at-ubtuw:3-4449
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tuw.author.orcid
0000-0002-8409-802X
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0000-0002-6340-4147
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0000-0002-1438-9462
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0000-0002-6018-3115
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tuw.author.orcid
0000-0002-8040-1677
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dc.rights.identifier
Urheberrechtsschutz
de
dc.rights.identifier
In Copyright
en
item.openairecristype
http://purl.org/coar/resource_type/c_2df8fbb1
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Open Access
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item.openairetype
research article
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with Fulltext
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en
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open
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E165-01-1 - Forschungsgruppe Modellkatalyse und angewandte Katalyse
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E164-01-1 - Forschungsgruppe Massenspektrometrische Bio- und Polymeranalytik
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E165 - Institut für Materialchemie
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