<div class="csl-bib-body">
<div class="csl-entry">Dworschak, D., Bishara, M., Cheng, H.-W., & Valtiner, M. (2022). Combining AFM imaging and elementally resolved spectroelectrochemistry for understanding stability and quality of passive films formed on Alloy 600. <i>Materials and Corrosion</i>, <i>73</i>(6), 842–850. https://doi.org/10.1002/maco.202112984</div>
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dc.identifier.issn
0947-5117
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/80262
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dc.description.abstract
Understanding elemental corrosion currents and visualizing corroding topographies provides a detailed insight into corrosion mechanisms at the nanoscale. Here, we develop a strategy to understand the elemental composition, corrosion resistivity, and local stability of passive materials. Specifically, we utilize a pulse voltammetry approach in a novel electrochemical atomic force microscopy (AFM) cell and complement this data by real-time dissolution currents based on spectroelectrochemical online analysis in an inductively coupled plasma mass spectroscopy (ICP-MS) flow cell. We study the oxide properties and their protective behavior when formed under different applied potentials using Alloy 600 as a model sample. Both AFM and ICP-MS data show that passive films formed on Alloy 600 at around +0.3 to +0.4 V in neutral 1 mM NaCl solution are most stable during anodic corrosion at +1.0 V, while AFM further demonstrates that local dissolution occurs, indicating locally varying defect levels in the passive film. In combination with both techniques, our approach provides real-time elementally resolved and localized information of passive film quality under corrosive conditions, and it may prove useful for other corroding materials.
en
dc.language.iso
en
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dc.publisher
WILEY-V C H VERLAG GMBH
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dc.relation.ispartof
Materials and Corrosion
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dc.rights.uri
https://creativecommons.org/licenses/by-nc/4.0/
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dc.subject
electrochemical AFM
en
dc.subject
electrochemical ICP-MS
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dc.subject
nickel base alloys
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dc.subject
passivation
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dc.subject
pulse voltammetry
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dc.title
Combining AFM imaging and elementally resolved spectroelectrochemistry for understanding stability and quality of passive films formed on Alloy 600
en
dc.type
Article
en
dc.type
Artikel
de
dc.rights.license
Creative Commons Namensnennung - Nicht kommerziell 4.0 International
de
dc.rights.license
Creative Commons Attribution - NonCommercial 4.0 International