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Yang, J., Puchberger, M., Qian, R., Maurer, C., & Schubert, U. (2012). Zinc(II) Complexes with Dangling Functional Organic Groups. European Journal of Inorganic Chemistry, 2012(27), 4294–4300. http://hdl.handle.net/20.500.12708/163925
Zinc(II) complexes with dangling functional organic groups were synthesized by reaction of zinc acetate with a series of bifunctional p-substituted benzene derivatives (a combination of carboxylate, oximate, amino, β-ketoimine, and salicylaldime groups). Selective coordination to carboxylate groups was observed when the second functional group was an oxime or β-ketoimine group. When the second group was an amine or salicylaldimine moiety, these groups were additionally coordinated. From the reaction with p-aminobenzoic acid, the compound [Zn2(OOCCH3)(OOC-C6H4-NH23]∞ was crystallized. It is a three-dimensional coordination polymer with bridging aminobenzoate ligands.
