<div class="csl-bib-body">
<div class="csl-entry">Schubert, U., & Stöger, B. (2024). The structural chemistry of titanyl oligomers and polymers. <i>Coordination Chemistry Reviews</i>, <i>498</i>, Article 215467. https://doi.org/10.1016/j.ccr.2023.215467</div>
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dc.identifier.issn
0010-8545
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/190110
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dc.description.abstract
Chain-like and cyclic structures of compounds with a ⋯Ti–O–Ti–O⋯ backbone are reviewed, that is, compounds in which the coordination octahedra of the titanium atoms share corners by means of μ2-O atoms. The charge of the TiO2+ unit is balanced by organic or inorganic ligands which additionally complete the coordination sphere of the titanium atoms. Typical substitution patterns are two mono-anionic bidentate ligands, two monodentate anionic plus two neutral ligands, or one tetradentate dianionic ligand. While only few examples of polymeric chain structures, or segments thereof, were structurally characterized, several types of cyclic compounds are known. This includes rings in which the Ti polyhedra are only linked via the μ2-O atoms, capped rings, or rings in which the titanium octahedra are additionally bridged by organic ligands.
en
dc.language.iso
en
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dc.publisher
Elsevier
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dc.relation.ispartof
Coordination Chemistry Reviews
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dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
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dc.subject
Metal oxo clusters
en
dc.subject
Titanyl compounds
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dc.subject
Cyclic structures
en
dc.title
The structural chemistry of titanyl oligomers and polymers
