<div class="csl-bib-body">
<div class="csl-entry">Biegger, F., Rameshan, C., Opitz, A. K., Noll, J., Haunold, T., Lang, H., & Barth, S. C. (2016). Thioether functionalised gallium and indium alkoxides in materials synthesis. <i>New Journal of Chemistry</i>, <i>40</i>, 6962–6969. https://doi.org/10.1039/C6NJ00402D</div>
</div>
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dc.identifier.issn
1144-0546
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dc.identifier.uri
http://hdl.handle.net/20.500.12708/20223
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dc.description.abstract
The thermolysis behaviour of a new class of metal alkoxides containing a thioether functionality in the alkyl chain is described. Homoleptic gallium alkoxides with sufficient volatility have been investigated in low pressure chemical vapour deposition (CVD) showing the potency of the thioether to act as a sulphidisation agent during decomposition of the precursor leading to Ga2O3−xSx films. Similar thermolysis experiments were conducted in high boiling point solvents leading to Ga2O3−xSx and In2O3−xSx particles. The thermolysis products have been investigated by SEM, EDX, XRD and XPS. Moreover, initial tests of the electrical transport properties of amorphous Ga2O3−xSx films have been conducted, showing increased conductivity and altered activation energies for the sulphur containing films.
en
dc.language.iso
en
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dc.publisher
ROYAL SOC CHEMISTRY
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dc.relation.ispartof
New Journal of Chemistry
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dc.rights.uri
http://creativecommons.org/licenses/by/3.0/
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dc.subject
thermolysis behavior
en
dc.title
Thioether functionalised gallium and indium alkoxides in materials synthesis
en
dc.type
Article
en
dc.type
Artikel
de
dc.rights.license
Creative Commons Attribution 3.0 Unported
en
dc.rights.license
Creative Commons Namensnennung 3.0 Unported
de
dc.contributor.affiliation
Technische Universität Chemnitz, Germany
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dc.contributor.affiliation
Technische Universität Chemnitz, Germany
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dc.description.startpage
6962
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dc.description.endpage
6969
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dcterms.dateSubmitted
2016-02-05
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dc.type.category
Original Research Article
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tuw.container.volume
40
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tuw.journal.peerreviewed
true
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tuw.peerreviewed
true
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wb.publication.intCoWork
International Co-publication
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tuw.researchinfrastructure
Universitäre Service-Einrichtung für Transmissionselektronenmikroskopie