Miksovsky, P., Horn, E. N., Naghdi, S., Eder, D., Schnürch, M., & Schröder, K. (2022, September). CONTINUOUS FORMATION OF CYCLIC LIMONENE CARBONATES USING SUPERCRITICAL CARBON DIOXIDE [Poster Presentation]. 9th IUPAC International Conference on Green Chemistry, Athen, Greece. http://hdl.handle.net/20.500.12708/81424
E163-03-5 - Forschungsgruppe Nachhaltige organische Synthese und Katalyse
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Datum (veröffentlicht):
Sep-2022
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Veranstaltungsname:
9th IUPAC International Conference on Green Chemistry
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Veranstaltungszeitraum:
5-Sep-2022 - 9-Sep-2022
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Veranstaltungsort:
Athen, Greece
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Keywords:
Renewables; Flow chemistry; CO2 Utilization
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Abstract:
We present a continuous flow method for converting limonene oxide and limonene dioxide to
limonene carbonates using carbon dioxide in its supercritical state as reagent and sole solvent.
Various ammonium-based ionic liquids were initially investigated in batch mode. For applying the
best performing and selective catalyst tetrabutylammonium chloride in continuous flow, the ionic
liquid was physisorbed on mesoporous silica as SILP catalyst. After optimization in short-term
experiments, the long-term stability of the SILP system was studied for 48 h.
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Projekt (extern):
ERC Carboflow
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Projektnummer:
Grant agreement No. 864991
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Forschungsschwerpunkte:
Materials Characterization: 10% Sustainable Production and Technologies: 40% Efficient Utilisation of Material Resources: 50%