Mikšovsky, P., Horn, E. N., Naghdi, S., Eder, D., Schnürch, M., & Bica-Schröder, K. (2022). Continuous Formation of Limonene Carbonates in Supercritical Carbon Dioxide. Organic Process Research and Development, 26(10), 2799–2810. https://doi.org/10.1021/acs.oprd.2c00143
We present a continuous flow method for the conversion of bioderived limonene oxide and limonene dioxide to limonene carbonates using carbon dioxide in its supercritical state as a reagent and sole solvent. Various ammonium- and imidazolium-based ionic liquids were initially investigated in batch mode. For applying the best-performing and selective catalyst tetrabutylammonium chloride in continuous flow, the ionic liquid was physisorbed on mesoporous silica. In addition to the analysis of surface area and pore size distribution of the best-performing supported ionic liquid phase (SILP) catalysts via nitrogen physisorption, SILPs were characterized by diffuse reflectance infrared Fourier transform spectroscopy and thermogravimetric analysis and served as heterogeneous catalysts in continuous flow. Initially, the continuous flow conversion was optimized in shortterm experiments resulting in the desired constant product outputs. Under these conditions, the long-term behavior of the SILP system was studied for a period of 48 h; no leaching of catalyst from the supporting material was observed in the case of limonene oxide and resulted in a yield of 16%. For limonene dioxide, just traces of leached catalysts were detected after reducing the catalyst loading from 30 to 15 wt %, thus enabling a constant product output in 17% yield over time.
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Project (external):
European Research Council (ERC)
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Project ID:
864991
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Research Areas:
Materials Characterization: 10% Sustainable Production and Technologies: 50% Efficient Utilisation of Material Resources: 40%