Fruit juices may contain harmful residues of pesticides that are associated with ecological and health risks. Thus, it is critical to develop sensitive and accurate methods for the monitoring of pesticides in these edible products. Undoubtedly, the development of environmentally friendly sample preparation protocols is at the forefront of research in analytical chemistry. In this work, a monolithic sol-gel polycaprolactone-polydimethylsiloxane-polycaprolactone (PCAP-PDMS-PCAP) sorbent platform was synthesized and used for the capsule phase microextraction (CPME) of pesticides from juices samples. Here, we propose a simple and sensitive CPME protocol combined with high-performance liquid chromatography-diode array detection (HPLC-DAD) for the monitoring of benzoyl urea pesticides in apple juice samples. Different monolithic sol-gel sorbent encapsulated CPME media were prepared and evaluated for their performance. Among them, sol-gel PCAP-PDMS-PCAP capsules showed the highest extraction efficiency towards the target analytes. The proposed method was optimized and validated in terms of accuracy, precision, limits of detection (LODs), limits of quantification and linearity. Under optimum conditions, the LODs for all analytes were 0.15-0.30 ng mL-1. The relative recoveries of the method ranged between 89.8% and 108.2%, showing good method accuracy. The precision of the CPME-HPLC-DAD method (expressed as relative standard deviation) was better than 8.0% for intra-day study and better than 9.1% for inter-day study. At a final step, the proposed method was successfully used for the monitoring of the target analytes in commercially available apple juice samples.